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100 1 _ |a Izarova, Natalya V.
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245 _ _ |a Classical/Non-classical Polyoxometalate Hybrids
260 _ _ |a Weinheim
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520 _ _ |a Two polyanions [SeI V2PdII4WVI14O56H]11− and [SeI V4PdII4WVI28O108H12]12− are the first hybrid polyoxometalates in which classical (Group 5/6 metal based) and non-classical (late transition-metal based) polyoxometalate units are joined. Requiring no supporting groups, this co-condensation of polyoxotungstate and isopolyoxopalladate constituents also provides a logical link between POM-PdII coordination complexes and the young subclass of polyoxopalladates. Solid-state, solution, and gas-phase studies suggest interesting specific reactivities for these hybrids and point to several potential derivatives and functionalization strategies.
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700 1 _ |a Santiago-Schübel, Beatrix
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700 1 _ |a Willbold, Sabine
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700 1 _ |a Hess, Volkmar
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700 1 _ |a Kögerler, Paul
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773 _ _ |a 10.1002/chem.201604238
|g Vol. 22, no. 45, p. 16052 - 16056
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