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100 1 _ |a Babelot, C.
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245 _ _ |a Crystallization processes, compressibility, sinterability and mechanical properties of La-monazite-type ceramics
260 _ _ |a Amsterdam [u.a.]
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520 _ _ |a Lanthanide orthophosphate ceramics with monazite structure gained broad interest for several industrial applications. The crystallization processes, compressibility and sinterability of monazite-type lanthanum orthophosphate powder hydrothermally synthesized at 200 °C as well as mechanical properties of the sintered compacts were investigated. Based on a combination of thermo- and surface area analyses, X-ray diffraction as well as scanning electron microscopy studies it was found that the crystallization process occurs at ∼500 °C and the final crystallization of LaPO4 monoclinic phase takes place at 1400 °C. The sintered pellets are characterized by a density of 98% of theoretical density, a Vickers hardness of 5.7 ± 0.1 GPa and fracture toughness of 1.4 ± 0.1 MPa m0.5.
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536 _ _ |a BMBF-02NUK021A - Verbundprojekt Conditioning: Grundlegende Untersuchungen zur Immobilisierung langlebiger Radionuklide mittels Einbau in endlagerrelevante Keramiken; Teilprojekt A (BMBF-02NUK021A)
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700 1 _ |a Bukaemskiy, Andrey
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700 1 _ |a Neumeier, S.
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700 1 _ |a Modolo, G.
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700 1 _ |a Bosbach, D.
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773 _ _ |a 10.1016/j.jeurceramsoc.2016.11.047
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