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000826675 1001_ $$0P:(DE-HGF)0$$aHuittinen, N.$$b0$$eCorresponding author
000826675 245__ $$aProbing structural homogeneity of La$_{1-x}$Gd$_{x}$PO$_{4}$ monazite-type solid solutions by combined spectroscopic and computational studies
000826675 260__ $$aAmsterdam [u.a.]$$bElsevier Science$$c2017
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000826675 520__ $$aHere we study the homogeneity of Eu3+-doped La1-xGdxPO4 (x = 0, 0.11, 0.33, 0.55, 0.75, 0.92, 1) monazite-type solid solutions by a combination of Raman and time-resolved laser fluorescence spectroscopies (TRLFS) with complementary quasi-random structure-based atomistic modeling studies. For the intermediate La0.45Gd0.55PO4 composition we detected a significant broadening of the Raman bands corresponding to the lattice vibrations of the LnO9 polyhedron, indicating much stronger distortion of the lanthanide cation site than the PO4 tetrahedron. A distortion of the crystal lattice around the dopant site was also confirmed in our TRLFS measurements of Eu3+ doped samples, where both the half width (FWHM) of the excitation peaks and the 7F2/7F1 ratio derived from the emission spectra increase for intermediate solid-solution compositions. The observed variation in FWHM correlates well with the simulated distribution of Eu···O bond distances within the investigated monazites. The combined results imply that homogenous Eu3+-doped La1-xGdxPO4 monazite-type solid solutions are formed over the entire composition range, which is of importance in the context of using these ceramics for immobilization of radionuclides.
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000826675 536__ $$0G:(DE-Juel1)jiek61_20131101$$aInvestigation of the new materials for safe management of high level nuclear waste. (jiek61_20131101)$$cjiek61_20131101$$fInvestigation of the new materials for safe management of high level nuclear waste.$$x2
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000826675 536__ $$0G:(DE-Juel1)jara0039_20121101$$aTowards controlled QCD transport coefficients (jara0039_20121101)$$cjara0039_20121101$$fTowards controlled QCD transport coefficients$$x4
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000826675 7001_ $$0P:(DE-Juel1)145894$$aArinicheva, Y.$$b1$$ufzj
000826675 7001_ $$0P:(DE-Juel1)137024$$aKowalski, Piotr$$b2$$ufzj
000826675 7001_ $$0P:(DE-Juel1)144348$$aVinograd, Victor$$b3$$ufzj
000826675 7001_ $$0P:(DE-Juel1)130389$$aNeumeier, Stefan$$b4$$ufzj
000826675 7001_ $$0P:(DE-Juel1)130324$$aBosbach, D.$$b5$$ufzj
000826675 773__ $$0PERI:(DE-600)2001279-2$$a10.1016/j.jnucmat.2017.01.024$$gVol. 486, p. 148 - 157$$p148 - 157$$tJournal of nuclear materials$$v486$$x0022-3115$$y2017
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