TY - JOUR
AU - Schmidt, Sandy
AU - Pedroso de Almeida, Tiago
AU - Rother, Dörte
AU - Hollmann, Frank
TI - Towards environmentally acceptable synthesis of chiral α-hydroxy ketones via oxidase-lyase cascades
JO - Green chemistry
VL - 19
IS - 5
SN - 1463-9270
CY - Cambridge
PB - RSC
M1 - FZJ-2017-01589
SP - 1226–1229
PY - 2017
AB - The one-pot multistep enzymatic oxidation of aliphatic andbenzylic alcohols to the corresponding aldehydes combined withtheir subsequent carboligation to chiral α-hydroxy ketones hasbeen exemplarily evaluated in terms of being a “green” biocatalyticapproach. Besides the potential to start from bio-derived alcohols,this concept avoids the direct use of the reactive aldehyde intermediates,enables addition of high substrate concentrations in oneliquid phase while maintaining enzyme activity and enables a simplifiedproduct isolation with diminished waste formation
LB - PUB:(DE-HGF)16
UR - <Go to ISI:>//WOS:000396144200003
DO - DOI:10.1039/C7GC00020K
UR - https://juser.fz-juelich.de/record/827464
ER -