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@ARTICLE{Paens:827723,
      author       = {Paßens, Michael and Moors, Marco and Karthäuser, Silvia
                      and Waser, R.},
      title        = {{E}nergy {L}evel {A}lignment at the {F}ullerene/{T}itanium
                      {O}xide {U}ltrathin {F}ilm {I}nterface},
      journal      = {The journal of physical chemistry / C},
      volume       = {121},
      number       = {5},
      issn         = {1932-7455},
      address      = {Washington, DC},
      publisher    = {Soc.},
      reportid     = {FZJ-2017-01831},
      pages        = {2815 - 2821},
      year         = {2017},
      abstract     = {The performance of molecule based electronic devices can be
                      improved by use of transition metal oxides (TMO) as charge
                      injection buffer layers between electrodes and organic
                      semiconductors. It is known that the appropriate energy
                      level alignment at the molecule/TMO interface determines the
                      efficiency of the respective TMO. Herein, scanning tunneling
                      microscopy is employed to characterize the interface formed
                      by fullerenes (C60) deposited on a titanium oxide (TiO)
                      ultrathin film, which is created by oxidation of a
                      Pt3Ti(111) surface. Individual C60 are identified with
                      orbital resolution, and the interfacial and intermolecular
                      interactions are characterized in detail. Furthermore, the
                      energy level alignment at the C60/TiO ultrathin film
                      interface is deduced based on scanning tunneling
                      spectroscopy data. The results demonstrate that the C60/TiO
                      interface corresponds to a type-I heterojunction and, thus,
                      is useful to decouple C60 molecules from the metallic alloy
                      surface.},
      cin          = {PGI-7 / JARA-FIT},
      ddc          = {540},
      cid          = {I:(DE-Juel1)PGI-7-20110106 / $I:(DE-82)080009_20140620$},
      pnm          = {524 - Controlling Collective States (POF3-524)},
      pid          = {G:(DE-HGF)POF3-524},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000394080900038},
      doi          = {10.1021/acs.jpcc.6b11386},
      url          = {https://juser.fz-juelich.de/record/827723},
}