Journal Article FZJ-2017-03112

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Nanocomposites of Highly Monodisperse Encapsulated Superparamagnetic Iron Oxide Nanocrystals Homogeneously Dispersed in a Poly(ethylene Oxide) Melt

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2017
Soc. Washington, DC

ACS nano 11(4), 3767–3775 () [10.1021/acsnano.6b08441]

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Abstract: Nanocomposite materials based on highly stable encapsulated superparamagnetic iron oxide nanocrystals (SPIONs) were synthesized and characterized by scattering methods and transmission electron microscopy (TEM). The combination of advanced synthesis and encapsulation techniques using different diblock copolymers and the thiol–ene click reaction for cross-linking the polymeric shell results in uniform hybrid SPIONs homogeneously dispersed in a poly(ethylene oxide) matrix. Small-angle X-ray scattering and TEM investigations demonstrate the presence of mostly single particles and a negligible amount of dyads. Consequently, an efficient control over the encapsulation and synthetic conditions is of paramount importance to minimize the fraction of agglomerates and to obtain uniform hybrid nanomaterials.

Keyword(s): Polymers, Soft Nano Particles and Proteins (1st) ; Soft Condensed Matter (2nd)

Classification:

Contributing Institute(s):
  1. Neutronenstreuung (ICS-1)
  2. Neutronenstreuung (Neutronenstreuung ; JCNS-1)
  3. Streumethoden (PGI-4)
  4. Streumethoden (JCNS-2)
  5. JCNS-FRM-II (JCNS (München) ; Jülich Centre for Neutron Science JCNS (München) ; JCNS-FRM-II)
Research Program(s):
  1. 551 - Functional Macromolecules and Complexes (POF3-551) (POF3-551)
  2. 6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623) (POF3-623)
  3. 6215 - Soft Matter, Health and Life Sciences (POF3-621) (POF3-621)
Experiment(s):
  1. TEM-MLZ: Transmission electron microscope at MLZ

Appears in the scientific report 2017
Database coverage:
Medline ; Current Contents - Physical, Chemical and Earth Sciences ; IF >= 10 ; JCR ; NCBI Molecular Biology Database ; No Authors Fulltext ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection
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The record appears in these collections:
Institute Collections > JCNS > JCNS-FRM-II
Document types > Articles > Journal Article
Institute Collections > JCNS > JCNS-2
Institute Collections > JCNS > JCNS-1
Institute Collections > IBI > IBI-8
Institute Collections > PGI > PGI-4
Workflow collections > Public records
ICS > ICS-1
Publications database

 Record created 2017-04-18, last modified 2025-01-29


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