Journal Article FZJ-2017-03454

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Evaluation of Thermodynamic Data and Phase Equlibria in the System Ca-Cr-Cu-Fe-Mg-Mn-S. Part II: Ternary and Quasi-Ternary Subsystems

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2017
Elsevier Science Amsterdam [u.a.]

Calphad 56, 286-302 () [10.1016/j.calphad.2017.01.007]

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Abstract: The Ca-Cr-Cu-Fe-Mg-Mn-S system has been thermodynamically assessed using all available experimental data. Sulfur is introduced into the thermodynamic description of 8 solid solution phases such as Thiospinel, Digenite, Oldhamite, Cu2S-I, Cu2S-II, Pyrrhotite, Brezinaite, Chalcopyrite-HT using available experimental information. Particular attention was given to the phase Pyrrhotite which forms at high temperatures a solid solution with end-members Fe1−xS and Cr1−xS in the ternary Cr-Fe-S system, and also the phase Digenite, which exhibits very wide solubility toward Pyrrhotite in the Cu-Fe-S system. In this part of the report ternary and quasi-ternary subsystems are presented while all relevant binary systems as well as pseudo-binary sections have already been presented in Part I of this series.

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Contributing Institute(s):
  1. Werkstoffstruktur und -eigenschaften (IEK-2)
Research Program(s):
  1. 111 - Efficient and Flexible Power Plants (POF3-111) (POF3-111)

Appears in the scientific report 2017
Database coverage:
Medline ; Current Contents - Engineering, Computing and Technology ; Current Contents - Physical, Chemical and Earth Sciences ; Ebsco Academic Search ; IF < 5 ; JCR ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection
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 Record created 2017-05-09, last modified 2024-07-11


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