| Home > Publications database > Evaluation of Thermodynamic Data and Phase Equlibria in the System Ca-Cr-Cu-Fe-Mg-Mn-S. Part II: Ternary and Quasi-Ternary Subsystems |
| Journal Article | FZJ-2017-03454 |
; ; ;
2017
Elsevier Science
Amsterdam [u.a.]
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Please use a persistent id in citations: doi:10.1016/j.calphad.2017.01.007
Abstract: The Ca-Cr-Cu-Fe-Mg-Mn-S system has been thermodynamically assessed using all available experimental data. Sulfur is introduced into the thermodynamic description of 8 solid solution phases such as Thiospinel, Digenite, Oldhamite, Cu2S-I, Cu2S-II, Pyrrhotite, Brezinaite, Chalcopyrite-HT using available experimental information. Particular attention was given to the phase Pyrrhotite which forms at high temperatures a solid solution with end-members Fe1−xS and Cr1−xS in the ternary Cr-Fe-S system, and also the phase Digenite, which exhibits very wide solubility toward Pyrrhotite in the Cu-Fe-S system. In this part of the report ternary and quasi-ternary subsystems are presented while all relevant binary systems as well as pseudo-binary sections have already been presented in Part I of this series.
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