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100 | 1 | _ | |a Beez, Alexander |0 P:(DE-Juel1)165688 |b 0 |e Corresponding author |
245 | _ | _ | |a Insight into the reaction mechanism of (La0.58Sr0.40)(Co0.20Fe0.80)O3-δ cathode with volatile chromium species at high current density in a solid oxide fuel cell stack |
260 | _ | _ | |a Pennington, NJ |c 2017 |b Electrochemical Soc. |
336 | 7 | _ | |a article |2 DRIVER |
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336 | 7 | _ | |a Journal Article |b journal |m journal |0 PUB:(DE-HGF)16 |s 1497876078_30050 |2 PUB:(DE-HGF) |
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520 | _ | _ | |a Anode-supported solid oxide fuel cells with different Cr protection layers on the metallic interconnect were operated in a short stack at 700°C for 1240 h. The current density was raised sequentially from 0.5 A cm−2 during the first 240 h of operation to 0.75 A cm−2 for a further 1000 h. After operation, the (La,Sr)(Co,Fe)O3-δ (LSCF) cathode layers were analyzed with respect to Cr interaction by both wet chemical and microstructural methods. For cells equipped with interconnects coated with a dense APS protection layer, the amount of Cr on the cathode was in the range of a few μg. For cells with a porous WPS coating on the interconnect, the amount of Cr was in the range of 110–160 μg cm−2 and Cr-containing phases were detected by SEM analysis both on top of the cathode layer and also at the LSCF/GDC interface, which has rarely been observed before. In addition, a deterioration of the cathode microstructure near the LSCF/GDC interface was observed. With respect to the high current density during operation, a theory was developed which explains both the Cr deposition at the LSCF/GDC interface and also the deterioration of the cathode. |
536 | _ | _ | |a 135 - Fuel Cells (POF3-135) |0 G:(DE-HGF)POF3-135 |c POF3-135 |f POF III |x 0 |
536 | _ | _ | |a SOFC - Solid Oxide Fuel Cell (SOFC-20140602) |0 G:(DE-Juel1)SOFC-20140602 |c SOFC-20140602 |f SOFC |x 1 |
536 | _ | _ | |0 G:(DE-Juel1)HITEC-20170406 |x 2 |c HITEC-20170406 |a HITEC - Helmholtz Interdisciplinary Doctoral Training in Energy and Climate Research (HITEC) (HITEC-20170406) |
700 | 1 | _ | |a Yin, Xiaoyan |0 P:(DE-Juel1)166023 |b 1 |u fzj |
700 | 1 | _ | |a Menzler, Norbert H. |0 P:(DE-Juel1)129636 |b 2 |u fzj |
700 | 1 | _ | |a Spatschek, Robert |0 P:(DE-Juel1)130979 |b 3 |u fzj |
700 | 1 | _ | |a Bram, Martin |0 P:(DE-Juel1)129591 |b 4 |u fzj |
773 | _ | _ | |a 10.1149/2.0051710JES |0 PERI:(DE-600)2002179-3 |n 10 |p F3028-F3034 |t Journal of the Electrochemical Society |v 164 |y 2017 |x 0013-4651 |
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