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037 _ _ |a FZJ-2017-03989
082 _ _ |a 540
100 1 _ |a Beez, Alexander
|0 P:(DE-Juel1)165688
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245 _ _ |a Insight into the reaction mechanism of (La0.58Sr0.40)(Co0.20Fe0.80)O3-δ cathode with volatile chromium species at high current density in a solid oxide fuel cell stack
260 _ _ |a Pennington, NJ
|c 2017
|b Electrochemical Soc.
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520 _ _ |a Anode-supported solid oxide fuel cells with different Cr protection layers on the metallic interconnect were operated in a short stack at 700°C for 1240 h. The current density was raised sequentially from 0.5 A cm−2 during the first 240 h of operation to 0.75 A cm−2 for a further 1000 h. After operation, the (La,Sr)(Co,Fe)O3-δ (LSCF) cathode layers were analyzed with respect to Cr interaction by both wet chemical and microstructural methods. For cells equipped with interconnects coated with a dense APS protection layer, the amount of Cr on the cathode was in the range of a few μg. For cells with a porous WPS coating on the interconnect, the amount of Cr was in the range of 110–160 μg cm−2 and Cr-containing phases were detected by SEM analysis both on top of the cathode layer and also at the LSCF/GDC interface, which has rarely been observed before. In addition, a deterioration of the cathode microstructure near the LSCF/GDC interface was observed. With respect to the high current density during operation, a theory was developed which explains both the Cr deposition at the LSCF/GDC interface and also the deterioration of the cathode.
536 _ _ |a 135 - Fuel Cells (POF3-135)
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536 _ _ |a SOFC - Solid Oxide Fuel Cell (SOFC-20140602)
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|a HITEC - Helmholtz Interdisciplinary Doctoral Training in Energy and Climate Research (HITEC) (HITEC-20170406)
700 1 _ |a Yin, Xiaoyan
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700 1 _ |a Menzler, Norbert H.
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700 1 _ |a Spatschek, Robert
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700 1 _ |a Bram, Martin
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773 _ _ |a 10.1149/2.0051710JES
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