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@ARTICLE{Arinicheva:835088,
      author       = {Arinicheva, Yulia and Popa, Karin and Scheinost, Andreas C.
                      and Rossberg, André and Dieste-Blanco, Oliver and Raison,
                      Philippe and Cambriani, Andrea and Somers, Joseph and
                      Bosbach, Dirk and Neumeier, Stefan},
      title        = {{S}tructural investigations of ({L}a,{P}u){PO}$_{4}$
                      monazite solid solutions: {XRD} and {XAFS} study},
      journal      = {Journal of nuclear materials},
      volume       = {493},
      issn         = {0022-3115},
      address      = {Amsterdam [u.a.]},
      publisher    = {Elsevier Science},
      reportid     = {FZJ-2017-04956},
      pages        = {404 - 411},
      year         = {2017},
      abstract     = {A solid state method was used to synthesize La1-xPuxPO4 (x
                      = 0.01, 0.05, 0.10, 0.15, (0.5)) solid solutions with
                      monazite structure. XRD measurements of the compounds with x
                      = 0.50 revealed the formation of two phases:
                      (La,Pu)PO4-monazite and a cubic phase (PuO2). Pure-phase
                      La1-xPuxPO4-monazite solid solutions were obtained for
                      materials with x = 0.00–0.15 and confirmed by a linear
                      dependence of the lattice parameters on composition
                      according to Vegard's law. X-ray absorption spectroscopy
                      (XAS) analysis at the Pu-LIII and La-LIII edges confirmed
                      the +III valence state of plutonium in the monazite solid
                      solutions. The local environment of Pu is PuPO4-like along
                      the solid solution series, except for the longest fitted
                      cation-cation distance, which may be an indication of
                      cluster formation consisting of a few Pu-atoms in the
                      La-Pu-monazite lattice.},
      cin          = {IEK-6},
      ddc          = {530},
      cid          = {I:(DE-Juel1)IEK-6-20101013},
      pnm          = {161 - Nuclear Waste Management (POF3-161) / BMBF-02NUK021A
                      - Verbundprojekt Conditioning: Grundlegende Untersuchungen
                      zur Immobilisierung langlebiger Radionuklide mittels Einbau
                      in endlagerrelevante Keramiken; Teilprojekt A
                      (BMBF-02NUK021A)},
      pid          = {G:(DE-HGF)POF3-161 / G:(DE-Juel1)BMBF-02NUK021A},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000408044000043},
      doi          = {10.1016/j.jnucmat.2017.06.034},
      url          = {https://juser.fz-juelich.de/record/835088},
}