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@ARTICLE{vandenHam:837639,
      author       = {van den Ham, Evert and Maino, Giulia and Bonneux, Gilles
                      and Marchal, Wouter and Elen, Ken and Gielis, Sven and
                      Mattelaer, Felix and Detavernier, Christophe and Notten,
                      Peter H. L. and Van Bael, Marlies and Hardy, An},
      title        = {{W}et-{C}hemical {S}ynthesis of 3{D} {S}tacked {T}hin
                      {F}ilm {M}etal-{O}xides for {A}ll-{S}olid-{S}tate {L}i-{I}on
                      {B}atteries},
      journal      = {Materials},
      volume       = {10},
      number       = {9},
      issn         = {1996-1944},
      address      = {Basel},
      publisher    = {MDPI},
      reportid     = {FZJ-2017-06517},
      pages        = {1072 -},
      year         = {2017},
      abstract     = {By ultrasonic spray deposition of precursors, conformal
                      deposition on 3D surfaces of tungsten oxide (WO3) negative
                      electrode and amorphous lithium lanthanum titanium oxide
                      (LLT) solid-electrolyte has been achieved as well as an
                      all-solid-state half-cell. Electrochemical activity was
                      achieved of the WO3 layers, annealed at temperatures of 500
                      °C. Galvanostatic measurements show a volumetric capacity
                      (415 mAh·cm−3) of the deposited electrode material. In
                      addition, electrochemical activity was shown for half-cells,
                      created by coating WO3 with LLT as the solid-state
                      electrolyte. The electron blocking properties of the LLT
                      solid-electrolyte was shown by ferrocene reduction. 3D
                      depositions were done on various micro-sized Si template
                      structures, showing fully covering coatings of both WO3 and
                      LLT. Finally, the thermal budget required for WO3 layer
                      deposition was minimized, which enabled attaining active WO3
                      on 3D TiN/Si micro-cylinders. A 2.6-fold capacity increase
                      for the 3D-structured WO3 was shown, with the same current
                      density per coated area.},
      cin          = {IEK-9},
      ddc          = {600},
      cid          = {I:(DE-Juel1)IEK-9-20110218},
      pnm          = {131 - Electrochemical Storage (POF3-131)},
      pid          = {G:(DE-HGF)POF3-131},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000411506700082},
      pubmed       = {pmid:28895931},
      doi          = {10.3390/ma10091072},
      url          = {https://juser.fz-juelich.de/record/837639},
}