TY - JOUR
AU - Reshetenko, Tatyana
AU - Kulikovsky, Andrei
TI - Impedance Spectroscopy Study of the PEM Fuel Cell Cathode with Nonuniform Nafion Loading
JO - Journal of the Electrochemical Society
VL - 164
IS - 11
SN - 0013-4651
CY - Pennington, NJ
PB - Electrochemical Soc.
M1 - FZJ-2017-06864
SP - E1-E6
PY - 2017
AB - We report modeling and experimental study of impedance of the PEM fuel cell cathode with nonuniform ionomer loading. A physics–based model for the high–frequency impedance is developed and analytical solution for impedance is derived. Assuming that the CCL proton conductivity σp exponentially decays from the membrane surface, we fit the model to experimental spectra of the cell measured at the open circuit conditions. Fitting gives the characteristic scale of the σp decay, the average CCL proton conductivity and the double layer capacitance.
LB - PUB:(DE-HGF)16
UR - <Go to ISI:>//WOS:000413263000050
DO - DOI:10.1149/2.0041711jes
UR - https://juser.fz-juelich.de/record/838192
ER -