Journal Article FZJ-2017-06864

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Impedance Spectroscopy Study of the PEM Fuel Cell Cathode with Nonuniform Nafion Loading

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2017
Electrochemical Soc. Pennington, NJ

Journal of the Electrochemical Society 164(11), E1-E6 () [10.1149/2.0041711jes]

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Abstract: We report modeling and experimental study of impedance of the PEM fuel cell cathode with nonuniform ionomer loading. A physics–based model for the high–frequency impedance is developed and analytical solution for impedance is derived. Assuming that the CCL proton conductivity σp exponentially decays from the membrane surface, we fit the model to experimental spectra of the cell measured at the open circuit conditions. Fitting gives the characteristic scale of the σp decay, the average CCL proton conductivity and the double layer capacitance.

Classification:

Contributing Institute(s):
  1. Elektrochemische Verfahrenstechnik (IEK-3)
Research Program(s):
  1. 135 - Fuel Cells (POF3-135) (POF3-135)

Appears in the scientific report 2017
Database coverage:
Medline ; Creative Commons Attribution CC BY 4.0 ; OpenAccess ; Current Contents - Engineering, Computing and Technology ; Current Contents - Physical, Chemical and Earth Sciences ; IF < 5 ; JCR ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection
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Document types > Articles > Journal Article
Institute Collections > ICE > ICE-2
Workflow collections > Public records
IEK > IEK-3
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Open Access

 Record created 2017-10-05, last modified 2024-07-11