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@ARTICLE{Hilbig:838403,
author = {Hilbig, Peter and Ibing, Lukas and Wagner, Ralf and Winter,
Martin and Cekic-Laskovic, Isidora},
title = {{E}thyl {M}ethyl {S}ulfone-{B}ased {E}lectrolytes for
{L}ithium {I}on {B}attery {A}pplications},
journal = {Energies},
volume = {10},
number = {9},
issn = {1996-1073},
address = {Basel},
publisher = {MDPI},
reportid = {FZJ-2017-07015},
pages = {1312 -},
year = {2017},
abstract = {Sulfone-based electrolytes, known for their higher
oxidative stability compared to the typically used organic
carbonate-based electrolytes, are considered promising
electrolytes for high voltage cathode materials towards the
objective of obtaining increased energy density in lithium
ion batteries. Nevertheless, sulfones suffer from high
viscosity as well as incompatibility with highly graphitic
anode materials, which limit their application. In this
paper, the effect of fluoroethylene carbonate (FEC) as an
electrolyte additive for the application of ethyl methyl
sulfone (EMS) electrolytes containing LiPF6 as conducting
salt, is studied in graphite-based cells by means of
selected electrochemical and spectroscopic methods. In
addition, influence of ethylene acetate (EA) as co-solvent
on the electrolyte viscosity and conductivity of the
EMS-based electrolytes is discussed, revealing improved
overall nickel cobalt manganese oxide (NMC)/graphite cell
performance. X-ray photoelectron spectroscopy (XPS)
measurements provide information about the surface chemistry
of the graphite electrodes after galvanostatic cycling. The
concept of EA as co-solvent is found to be applicable for
other sulfones such as isopropyl methyl sulfone (MeiPrSO2)
and ethyl isopropyl sulfone (EtiPrSO2).},
cin = {IEK-12},
ddc = {620},
cid = {I:(DE-Juel1)IEK-12-20141217},
pnm = {131 - Electrochemical Storage (POF3-131)},
pid = {G:(DE-HGF)POF3-131},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000411225200068},
doi = {10.3390/en10091312},
url = {https://juser.fz-juelich.de/record/838403},
}