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@ARTICLE{Friesen:838473,
author = {Friesen, Alex and Mönnighoff, Xaver and Börner, Markus
and Haetge, Jan and Schappacher, Falko M. and Winter,
Martin},
title = {{I}nfluence of temperature on the aging behavior of
18650-type lithium ion cells: {A} comprehensive approach
combining electrochemical characterization and post-mortem
analysis},
journal = {Journal of power sources},
volume = {342},
issn = {0378-7753},
address = {New York, NY [u.a.]},
publisher = {Elsevier},
reportid = {FZJ-2017-07076},
pages = {88 - 97},
year = {2017},
abstract = {The understanding of the aging behavior of lithium ion
batteries in automotive and energy storage applications is
essential for the acceptance of the technology. Therefore,
aging experiments were conducted on commercial 18650-type
state-of-the-art cells to determine the influence of the
temperature during electrochemical cycling on the aging
behavior of the different cell components. The cells, based
on Li(Ni0.5Co0.2Mn0.3)O2 (NCM532)/graphite, were aged at 20
°C and 45 °C to different states of health. The
electrochemical performance of the investigated cells shows
remarkable differences depending on the cycling temperature.
At contrast to the expected behavior, the cells cycled at 45
°C show a better electrochemical performance over lifetime
than the cells cycled at 20 °C. Comprehensive post-mortem
analyses revealed the main aging mechanisms, showing a
complex interaction between electrodes and electrolyte. The
main aging mechanisms of the cells cycled at 45 °C differ
strongly at contrast to cells cycled at 20 °C. A strong
correlation between the formed SEI, the electrolyte
composition and the electrochemical performance over
lifetime was observed.},
cin = {IEK-12},
ddc = {620},
cid = {I:(DE-Juel1)IEK-12-20141217},
pnm = {131 - Electrochemical Storage (POF3-131)},
pid = {G:(DE-HGF)POF3-131},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000396186300012},
doi = {10.1016/j.jpowsour.2016.12.040},
url = {https://juser.fz-juelich.de/record/838473},
}