% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{Weinrich:841125,
      author       = {Weinrich, Henning and Come, Jérémy and Tempel, Hermann
                      and Kungl, Hans and Eichel, Rüdiger-A. and Balke, Nina},
      title        = {{U}nderstanding the nanoscale redox-behavior of iron-anodes
                      for rechargeable iron-air batteries},
      journal      = {Nano energy},
      volume       = {41},
      issn         = {2211-2855},
      address      = {Amsterdam [u.a.]},
      publisher    = {Elsevier},
      reportid     = {FZJ-2017-08225},
      pages        = {706 - 716},
      year         = {2017},
      abstract     = {Iron-air cells provide a promising and resource-efficient
                      alternative battery concept with superior area specific
                      power density characteristics compared to state-of-the-art
                      Li-air batteries and potentially superior energy density
                      characteristics compared to present Li-ion batteries.
                      Understanding charge-transfer reactions at the
                      anode-electrolyte interface is the key to develop
                      high-performance cells. By employing in-situ electrochemical
                      atomic force microscopy (in-situ EC-AFM), in-depth insight
                      into the electrochemically induced surface reaction
                      processes on iron in concentrated alkaline electrolyte is
                      obtained. The results highlight the formation and growth of
                      the redox-layer on iron over the course of several
                      oxidation/reduction cycles. By this means, a direct
                      correlation between topography changes and the corresponding
                      electrochemical reactions at the nanoscale could
                      unambiguously be established. Here, the twofold character of
                      the nanoparticulate redox-layer in terms of its passivating
                      character and its contribution to the electrochemical
                      reactions is elucidated. Furthermore, the evolution of
                      single nanoparticles on the iron electrode surface is
                      evaluated in unprecedented and artifact-free detail. Based
                      on the dedicated topography analysis, a detailed structural
                      model for the evolution of the redox-layer which is likewise
                      elementary for corrosion science and battery research is
                      derived.},
      cin          = {IEK-9},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IEK-9-20110218},
      pnm          = {131 - Electrochemical Storage (POF3-131) / HITEC -
                      Helmholtz Interdisciplinary Doctoral Training in Energy and
                      Climate Research (HITEC) (HITEC-20170406)},
      pid          = {G:(DE-HGF)POF3-131 / G:(DE-Juel1)HITEC-20170406},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000415302600078},
      doi          = {10.1016/j.nanoen.2017.10.023},
      url          = {https://juser.fz-juelich.de/record/841125},
}