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@ARTICLE{Jalowicka:841331,
      author       = {Jalowicka, A. and Nowak, W. J. and Naumenko, D. and
                      Quadakkers, W. J.},
      title        = {{E}ffect of {SO}2 {A}ddition on {A}ir {O}xidation
                      {B}ehavior of {CM}247 and {CMSX}-4 at 1050°{C}},
      journal      = {JOM},
      volume       = {68},
      number       = {11},
      issn         = {1543-1851},
      address      = {New York, NY},
      publisher    = {Springer Science + Business Media},
      reportid     = {FZJ-2017-08416},
      pages        = {2776 - 2785},
      year         = {2016},
      abstract     = {In the present work, the oxidation behavior of two
                      commercial Ni-base superalloys, CMSX-4 and CM247, in
                      synthetic air with and without 2 $vol.\%$ SO2 at 1050°C has
                      been studied. The corrosion reactions in the presence of SO2
                      could not be explained simply in terms of the contents of
                      the main scale‐forming alloying elements, Cr and Al. The
                      far better resistance of CMSX-4 is related to the formation
                      of a rather pure and dense alumina scale after a very short
                      period of transient oxidation. Rapid development of an
                      alumina scale prevents access of molecular SO2 to the metal
                      surface thus effectively suppressing internal sulfidation.
                      In contrast, CM247 with a similar Al-content formed an
                      Al-rich oxide scale with local intrusions and/or
                      inhomogeneities caused by the underlying alloy
                      microstructure, which deteriorated its resistance to
                      internal sulfidation and resulted in rapid failure in
                      synthetic air + $2\%$ SO2.},
      cin          = {IEK-2},
      ddc          = {670},
      cid          = {I:(DE-Juel1)IEK-2-20101013},
      pnm          = {111 - Efficient and Flexible Power Plants (POF3-111)},
      pid          = {G:(DE-HGF)POF3-111},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000388816100012},
      doi          = {10.1007/s11837-016-2072-1},
      url          = {https://juser.fz-juelich.de/record/841331},
}