TY - JOUR AU - Valerius, Philipp AU - Herbig, Charlotte AU - Will, Moritz AU - Arman, Mohammad A. AU - Knudsen, Jan AU - Caciuc, Vasile AU - Atodiresei, Nicolae AU - Michely, Thomas TI - Annealing of ion-irradiated hexagonal boron nitride on Ir(111) JO - Physical review / B VL - 96 IS - 23 SN - 2469-9950 CY - Woodbury, NY PB - Inst. M1 - FZJ-2017-08656 SP - 235410 PY - 2017 AB - Annealing of a monolayer of hexagonal boron nitride destroyed by Xe ion irradiation gives rise to rich structural phenomena investigated here through a combination of scanning tunneling microscopy, low-energy electron diffraction, x-ray photoelectron spectroscopy, and density functional theory calculations. We find selective pinning of vacancy clusters at a single specific location within the moiré formed by hexagonal boron nitride (h-BN) and the Ir substrate, crystalline Xe at room temperature of monolayer and bilayer thickness sealed inside h-BN blisters, standalone blisters only bound to the metal at temperatures where boron nitride on Ir(111) decomposes, and finally a pronounced threefold symmetry of all morphological features due to the preferential formation of boron-terminated zigzag edges that firmly bind to the substrate. The investigations give clear insight into the relevance of the substrate for the damage creation and annealing in a two-dimensional layer material. LB - PUB:(DE-HGF)16 UR - <Go to ISI:>//WOS:000417487200004 DO - DOI:10.1103/PhysRevB.96.235410 UR - https://juser.fz-juelich.de/record/841621 ER -