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@ARTICLE{Panchenko:843775,
author = {Panchenko, Olha and Borgardt, Elena and Zwaygardt, Walter
and Hackemüller, Franz Josef and Bram, Martin and
Kardjilov, Nikolay and Arlt, Tobias and Manke, Ingo and
Müller, Martin and Stolten, Detlef and Lehnert, Werner},
title = {{I}n-situ two-phase flow investigation of different porous
transport layer for a polymer electrolyte membrane ({PEM})
electrolyzer with neutron spectroscopy},
journal = {Journal of power sources},
volume = {390},
issn = {0378-7753},
address = {New York, NY [u.a.]},
publisher = {Elsevier},
reportid = {FZJ-2018-01318},
pages = {108-115},
year = {2018},
abstract = {Electrolysis with polymer electrolyte membranes (PEMs)
plays an increasingly important role in the development of
inconsistent renewable energy technologies and seasonal
storage. An effect that reduces the efficiency of PEM
electrolysis is the mass transport limitation (MTL), which
occurs at higher current densities and leads to a sudden
increase in cell potentials. The oxygen generated on the
anode side prevents the water from being supplied to the
catalyst. Neutron-based imaging (neutron visualization
techniques) make it possible to visualize mass transfer
processes in the porous transport layer (PTL). When PTL
materials are varied and operating modes used, it is
possible to investigate the critical point at which the MTL
is generated. This paper presents the results of neutron
radiography measurements. In the course of the measurements,
we have observed PEM electrolysis cells in operation, using
different materials as anode PTL. The PTLs are metal plates
made of sintered titanium particles, as well as titanium
fiber. During the measurements, it was possible to visualize
the water-gas distribution in the cell during operation in
order to understand the mechanisms of mass transport.},
cin = {IEK-3},
ddc = {620},
cid = {I:(DE-Juel1)IEK-3-20101013},
pnm = {134 - Electrolysis and Hydrogen (POF3-134)},
pid = {G:(DE-HGF)POF3-134},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000434748000014},
doi = {10.1016/j.jpowsour.2018.04.044},
url = {https://juser.fz-juelich.de/record/843775},
}