TY  - JOUR
AU  - Bläsing, Marc
AU  - Abascal, Maria Benito
AU  - Ninomiya, Yoshihiko
AU  - Müller, Michael
TI  - Partitioning of Lead and Lead Compounds under Gasification-Like Conditions
JO  - Energy & fuels
VL  - 32
IS  - 1
SN  - 1520-5029
CY  - Columbus, Ohio
PB  - American Chemical Society
M1  - FZJ-2018-02202
SP  - 651 - 657
PY  - 2018
AB  - An investigation of the chemical form, the concentration, and distribution of lead species between the gas and condensed phase was carried out under gasification-like conditions. The influence of hydrogen sulfide, hydrogen chloride, and steam on the speciation of lead was studied. The gaseous species were determined online by molecular-beam-mass-spectrometry. The condensates were analyzed by standard methods. The dominant chemical forms were metallic Pb, PbCl2, and PbS. The experimental data were compared with the results of thermodynamic Scheil–Gulliver cooling calculations. Further, the experimental data was used as an input for a pseudoequilibrium model aiming at the determination of kinetic information on the underlying transformations.
LB  - PUB:(DE-HGF)16
UR  - <Go to ISI:>//WOS:000423253200068
DO  - DOI:10.1021/acs.energyfuels.7b02803
UR  - https://juser.fz-juelich.de/record/844851
ER  -