TY - JOUR
AU - Uhlenbruck, Sven
AU - Dellen, Christian
AU - Möller, Sören
AU - Lobe, Sandra
AU - Tsai, Chih-Long
AU - Finsterbusch, Martin
AU - Bram, Martin
AU - Guillon, Olivier
TI - Reactions of garnet-based solid-state lithium electrolytes with water — A depth-resolved study
JO - Solid state ionics
VL - 320
SN - 0167-2738
CY - Amsterdam [u.a.]
PB - Elsevier Science
M1 - FZJ-2018-02666
SP - 259 - 265
PY - 2018
AB - Garnet Li6.4La3Zr1.6Ta0.4O12 thin films prepared by magnetron sputtering were analysed by secondary ion mass spectrometry, nuclear reaction analysis and Rutherford backscattering to identify, localize and quantify the reactions associated with the presence of low amounts of water and carbon dioxide. Samples in a pristine state and after storage in an Argon-filled glove box for months were compared. Both, lithium hydroxide and lithium carbonate were detected, with carbon-containing species and hydrogen-containing having surprisingly different depth profiles.
LB - PUB:(DE-HGF)16
UR - <Go to ISI:>//WOS:000436219600033
DO - DOI:10.1016/j.ssi.2018.03.004
UR - https://juser.fz-juelich.de/record/845395
ER -