Journal Article FZJ-2018-02666

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Reactions of garnet-based solid-state lithium electrolytes with water — A depth-resolved study

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2018
Elsevier Science Amsterdam [u.a.]

Solid state ionics 320, 259 - 265 () [10.1016/j.ssi.2018.03.004]

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Abstract: Garnet Li6.4La3Zr1.6Ta0.4O12 thin films prepared by magnetron sputtering were analysed by secondary ion mass spectrometry, nuclear reaction analysis and Rutherford backscattering to identify, localize and quantify the reactions associated with the presence of low amounts of water and carbon dioxide. Samples in a pristine state and after storage in an Argon-filled glove box for months were compared. Both, lithium hydroxide and lithium carbonate were detected, with carbon-containing species and hydrogen-containing having surprisingly different depth profiles.

Classification:

Contributing Institute(s):
  1. Werkstoffsynthese und Herstellungsverfahren (IEK-1)
  2. JARA-ENERGY (JARA-ENERGY)
Research Program(s):
  1. 131 - Electrochemical Storage (POF3-131) (POF3-131)

Appears in the scientific report 2018
Database coverage:
Embargoed OpenAccess ; Current Contents - Physical, Chemical and Earth Sciences ; Ebsco Academic Search ; IF < 5 ; JCR ; NationallizenzNationallizenz ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection
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Document types > Articles > Journal Article
JARA > JARA > JARA-JARA\-ENERGY
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IEK > IEK-1
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Open Access

 Record created 2018-04-26, last modified 2024-07-11


Published on 2018-03-01. Available in OpenAccess from 2020-03-01.:
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