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000849646 1001_ $$0P:(DE-Juel1)144923$$aDeibert, Wendelin$$b0$$eCorresponding author
000849646 245__ $$aEffect of microstructure on electrical and mechanical properties of La 5.4 WO 12-δ proton conductor
000849646 260__ $$aAmsterdam [u.a.]$$bElsevier Science$$c2018
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000849646 520__ $$aThe relationships between microstructural characteristics and electrical as well as mechanical properties of La5.4WO12-δ (LWO54) materials were studied. Polycrystalline LWO54 samples revealed identical transport mechanisms regardless of the sample microstructure. The studied samples show predominately proton conductor behaviour below 800 °C and become predominant n-type and oxygen ion conductors above this temperature. The magnitude of the total conductivity is enhanced with larger grain size and lower porosity. Young’s modulus decreased by 20% with increasing temperature up to 1000 °C regardless of grain size and atmosphere. Fracture strength was determined via ring-on-ring bending tests, yielding values that strongly depended on microstructural characteristics and homogeneity of the microstructure. Elevated temperature deformation studies revealed that creep is governed by cation diffusion mechanism.
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000849646 7001_ $$0P:(DE-Juel1)145779$$aStournari, Vasiliki$$b1
000849646 7001_ $$0P:(DE-HGF)0$$aIvanova, Mariya E.$$b2
000849646 7001_ $$0P:(DE-HGF)0$$aEscolástico, Sonia$$b3
000849646 7001_ $$0P:(DE-HGF)0$$aSerra, José M.$$b4
000849646 7001_ $$0P:(DE-Juel1)129755$$aMalzbender, Jürgen$$b5
000849646 7001_ $$0P:(DE-Juel1)129685$$aBeck, Tilmann$$b6
000849646 7001_ $$0P:(DE-Juel1)129795$$aSingheiser, Lorenz$$b7
000849646 7001_ $$0P:(DE-Juel1)161591$$aGuillon, Olivier$$b8
000849646 7001_ $$0P:(DE-Juel1)129637$$aMeulenberg, Wilhelm A.$$b9
000849646 773__ $$0PERI:(DE-600)2013983-4$$a10.1016/j.jeurceramsoc.2018.04.009$$gVol. 38, no. 10, p. 3527 - 3538$$n10$$p3527 - 3538$$tJournal of the European Ceramic Society$$v38$$x0955-2219$$y2018
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