| Hauptseite > Publikationsdatenbank > Effect of microstructure on electrical and mechanical properties of La 5.4 WO 12-δ proton conductor > print |
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| 100 | 1 | _ | |a Deibert, Wendelin |0 P:(DE-Juel1)144923 |b 0 |e Corresponding author |
| 245 | _ | _ | |a Effect of microstructure on electrical and mechanical properties of La 5.4 WO 12-δ proton conductor |
| 260 | _ | _ | |a Amsterdam [u.a.] |c 2018 |b Elsevier Science |
| 336 | 7 | _ | |a article |2 DRIVER |
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| 520 | _ | _ | |a The relationships between microstructural characteristics and electrical as well as mechanical properties of La5.4WO12-δ (LWO54) materials were studied. Polycrystalline LWO54 samples revealed identical transport mechanisms regardless of the sample microstructure. The studied samples show predominately proton conductor behaviour below 800 °C and become predominant n-type and oxygen ion conductors above this temperature. The magnitude of the total conductivity is enhanced with larger grain size and lower porosity. Young’s modulus decreased by 20% with increasing temperature up to 1000 °C regardless of grain size and atmosphere. Fracture strength was determined via ring-on-ring bending tests, yielding values that strongly depended on microstructural characteristics and homogeneity of the microstructure. Elevated temperature deformation studies revealed that creep is governed by cation diffusion mechanism. |
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