Journal Article FZJ-2018-05640

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Assembly of Ring-Shaped Phosphorus within Carbon Nanotube Nanoreactors

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2017
Wiley-VCH65543 Weinheim

Angewandte Chemie 129(7), 1876 - 1880 () [10.1002/ange.201611740]

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Abstract: A phosphorus allotrope that has not been observed so far, ring‐shaped phosphorus consisting of alternate P8 and P2 structural units, has been assembled inside multi‐walled carbon nanotube nanoreactors with inner diameters of 5–8 nm by a chemical vapor transport and reaction of red phosphorus at 500 °C. The ring‐shaped nanostructures with surrounding graphene walls are stable under ambient conditions. The nanostructures were characterized by high‐resolution transmission electron microscopy, scanning transmission electron microscopy, energy‐dispersive X‐ray spectroscopy, Raman scattering, attenuated total reflectance Fourier transform infrared spectroscopy, and X‐ray photoelectron spectroscopy.

Classification:

Contributing Institute(s):
  1. Physik Nanoskaliger Systeme (ER-C-1)
  2. Materialwissenschaft u. Werkstofftechnik (ER-C-2)
Research Program(s):
  1. 143 - Controlling Configuration-Based Phenomena (POF3-143) (POF3-143)

Appears in the scientific report 2018
Database coverage:
Medline ; NCBI Molecular Biology Database ; NationallizenzNationallizenz ; SCOPUS
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 Record created 2018-10-02, last modified 2021-01-29


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