Home > Publications database > Assembly of Ring-Shaped Phosphorus within Carbon Nanotube Nanoreactors |
Journal Article | FZJ-2018-05640 |
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2017
Wiley-VCH65543
Weinheim
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Please use a persistent id in citations: doi:10.1002/ange.201611740
Abstract: A phosphorus allotrope that has not been observed so far, ring‐shaped phosphorus consisting of alternate P8 and P2 structural units, has been assembled inside multi‐walled carbon nanotube nanoreactors with inner diameters of 5–8 nm by a chemical vapor transport and reaction of red phosphorus at 500 °C. The ring‐shaped nanostructures with surrounding graphene walls are stable under ambient conditions. The nanostructures were characterized by high‐resolution transmission electron microscopy, scanning transmission electron microscopy, energy‐dispersive X‐ray spectroscopy, Raman scattering, attenuated total reflectance Fourier transform infrared spectroscopy, and X‐ray photoelectron spectroscopy.
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