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@ARTICLE{Zhang:856715,
      author       = {Zhang, J. and Garcia-Fresnillo, L. and Jalowicka, A. and
                      Pillai, R. and Naumenko, D. and Quadakkers, W. J.},
      title        = {{P}hase {T}ransformations in {C}o-{N}i-{C}r-{W} {A}lloys
                      {D}uring {H}igh {T}emperature {E}xposure to {S}team
                      {E}nvironment},
      journal      = {Journal of phase equilibria and diffusion},
      volume       = {39},
      number       = {4},
      issn         = {1863-7345},
      address      = {Boston, Mass.},
      publisher    = {Springer},
      reportid     = {FZJ-2018-06066},
      pages        = {387 - 400},
      year         = {2018},
      abstract     = {Three model alloys, Co-10Ni-20Cr-15W, Co-30Ni-20Cr-15W and
                      Ni-20Cr-15W (all in $wt.\%)$ were investigated in
                      $Ar-50\%H2O$ at 700 and 750 °C for up to 3000 h reaction.
                      The results showed the formation of thin chromia scales on
                      the sample surfaces in all cases. For the Co-base alloys,
                      accompanied by the Cr2O3 formation, a chromium depletion
                      zone was detected underneath the oxide scale along with Co3W
                      with some amount of dissolved Cr and Ni. This kind of Co3W
                      was enriched along the oxide/alloy interface. The formation
                      of this intermetallic phase was considered to follow
                      nucleation and subsequent growth based on morphology and
                      composition analyses. Increasing nickel content reduced the
                      amount of Co3W formation. For the nickel-base alloy
                      Ni-20Cr-15W, no intermetallic phase was detected. The
                      formation of the Co3W intermetallic was discussed based on
                      phase transformation induced by chromium depletion. The
                      effect of nickel on this phenomenon was also discussed
                      according to thermodynamic phase equilibrium analysis.},
      cin          = {IEK-2},
      ddc          = {530},
      cid          = {I:(DE-Juel1)IEK-2-20101013},
      pnm          = {111 - Efficient and Flexible Power Plants (POF3-111)},
      pid          = {G:(DE-HGF)POF3-111},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000441127400004},
      doi          = {10.1007/s11669-018-0647-y},
      url          = {https://juser.fz-juelich.de/record/856715},
}