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@ARTICLE{Lang:857059,
      author       = {Lang, Christian and Hendricks, Jan and Zhang, Zhenkun and
                      Reddy, Naveen K. and Rothstein, Jonathan P. and Lettinga, M.
                      Paul and Vermant, Jan and Clasen, Christian},
      title        = {{E}ffects of particle stiffness on the extensional rheology
                      of model rod-like nanoparticle suspensions},
      journal      = {Soft matter},
      volume       = {15},
      number       = {5},
      issn         = {1744-683X},
      address      = {London},
      publisher    = {Royal Soc. of Chemistry},
      reportid     = {FZJ-2018-06327},
      pages        = {833-841},
      year         = {2019},
      abstract     = {The linear and nonlinear rheological behavior of two
                      rod-like particle suspensions as a function of concentration
                      is studied using small amplitude oscillatory shear, steady
                      shear and capillary breakup extensional rheometry. The
                      rod-like suspensions are composed of fd virus and its mutant
                      fdY21M, which are perfectly monodisperse, with a length on
                      the order of 900 nm. The particles are semiflexible yet
                      differ in their persistence length. The effect of stiffness
                      on the rheological behavior in both, shear and extensional
                      flow, is investigated experimentally. The linear
                      viscoelastic shear data is compared in detail with
                      theoretical predictions for worm-like chains. The
                      extensional properties are compared to Batchelor's theory,
                      generalized for the shear thinning nature of the
                      suspensions. Theoretical predictions agree well with the
                      measured complex moduli at low concentrations as well as the
                      nonlinear shear and elongational viscosities at high flow
                      rates. The results in this work provide guidelines for
                      enhancing the elongational viscosity based on purely
                      frictional effects in the absence of strong normal forces
                      which are characteristic for high molecular weight
                      polymers.},
      cin          = {ICS-3},
      ddc          = {530},
      cid          = {I:(DE-Juel1)ICS-3-20110106},
      pnm          = {551 - Functional Macromolecules and Complexes (POF3-551)},
      pid          = {G:(DE-HGF)POF3-551},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:30488939},
      UT           = {WOS:000457540000022},
      doi          = {10.1039/C8SM01925H},
      url          = {https://juser.fz-juelich.de/record/857059},
}