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@ARTICLE{Kolek:857792,
      author       = {Kolek, Martin and Otteny, Fabian and Becking, Jens and
                      Winter, Martin and Esser, Birgit and Bieker, Peter},
      title        = {{M}echanism of {C}harge/{D}ischarge of
                      {P}oly(vinylphenothiazine)-{B}ased {L}i–{O}rganic
                      {B}atteries},
      journal      = {Chemistry of materials},
      volume       = {30},
      number       = {18},
      issn         = {1520-5002},
      address      = {Washington, DC},
      publisher    = {American Chemical Society},
      reportid     = {FZJ-2018-06759},
      pages        = {6307 - 6317},
      year         = {2018},
      abstract     = {Organic electrode materials are among the promising next
                      generation compounds for battery energy storage as a greener
                      and cheaper alternative to transition-metal-based
                      electrodes. A prominent class among them are redox polymers,
                      which can reversibly store energy and can be capable of fast
                      redox processes. Nevertheless, drawbacks are their often low
                      specific energy and lifetime. A main challenge is their
                      solubility in battery electrolytes, which is detrimental to
                      cell performance. Herein, we discuss the solubility
                      properties of a polyvinyl-based redox polymer with a
                      methylphenothiazine side group (PVMPT) in
                      organic-solvent-based battery electrolytes and generate new
                      insights into the mechanism of the redeposition process of
                      dissolved active material. We addressed the mechanistic
                      studies of this “polymer–electrolyte cross-talk” with
                      microscopic and spectroscopic methods. These findings are
                      important for the molecular design of new organic electrode
                      materials, since the redeposited polymer showed improved
                      cycling performance and outstanding cycling stabilities. We
                      herein aim to draw a bigger picture of the solubility of
                      redox polymers and its consequences and motivate the
                      scientific community to reconsider the common conception of
                      the deteriorating nature of the solubility of organic
                      battery electrode materials.},
      cin          = {IEK-12},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IEK-12-20141217},
      pnm          = {131 - Electrochemical Storage (POF3-131)},
      pid          = {G:(DE-HGF)POF3-131},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000445972100013},
      doi          = {10.1021/acs.chemmater.8b02015},
      url          = {https://juser.fz-juelich.de/record/857792},
}