Journal Article FZJ-2018-07261

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Predicting Effect of Base Alloy Composition on Oxidation- and Interdiffusion-Induced Degradation of an MCrAlY Coating

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2018
TMS [S.l.]

JOM 70(8), 1520 - 1526 () [10.1007/s11837-018-2950-9]

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Abstract: The effect of two base alloys, viz. Ni-based superalloy Rene 80 and Co-based alloy ECY768, on the oxidation and interdiffusion behavior of a NiCoCrAlY Re-containing coating after exposure for up to 2000 h at 1050°C in synthetic air has been evaluated. Scanning electron microscopy with energy-dispersive x-ray spectroscopy was employed to measure the element concentrations, and phases were identified by electron backscatter diffraction. Significant depletion of β-NiAl within the coating, enrichment of γ′-phase, and formation of µ-phase in the alloy and Kirkendall porosity at the coating–alloy interface were observed in the coating on Rene 80. In contrast, the coating on the Co-base alloy ECY768 formed large amounts of Cr/Re-rich carbides and the depletion of β-NiAl phase was less pronounced than that observed on the Ni-base alloy. These findings could be interpreted using an in-house-developed thermodynamic–kinetic CALPHAD-based computer model.

Classification:

Contributing Institute(s):
  1. Werkstoffstruktur und -eigenschaften (IEK-2)
Research Program(s):
  1. 111 - Efficient and Flexible Power Plants (POF3-111) (POF3-111)

Appears in the scientific report 2018
Database coverage:
Medline ; Clarivate Analytics Master Journal List ; Current Contents - Engineering, Computing and Technology ; IF < 5 ; JCR ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Web of Science Core Collection
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 Record created 2018-12-11, last modified 2024-07-11


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