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000858632 1001_ $$0P:(DE-Juel1)169869$$aSchmitz, Sebastian$$b0
000858632 245__ $$aTriangular {Ni3} coordination cluster with a ferromagnetically coupled metal-ligand core
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000858632 520__ $$aThe coordination characteristics of a tridentate, π-conjugated Schiff base (HL·SMe) combined with 4-(methylthio)benzoic acid (Hbza·SMe) were explored in methanol solution. A two-step aerobic process involving the precursor NiCl2·6H2O afforded the trinuclear coordination compound [NiII3(L·SMe)4(bza·SMe)(MeOH)2]Cl0.5(CH3O)0.5·5.5MeOH·H2O (1), while the precursor Ni(ClO4)2·6H2O resulted in [NiII3(L·SMe)4(bza·SMe)(MeOH)2](ClO4)0.75(CH3O)0.25·1.5MeOH·0.75H2O (2); in both cases the thioether-containing ligands are key to isolation of crystalline products. Their solvent-free cationic motif [Ni3(L·SMe)4(bza·SMe)]+, supported by two different types of monodeprotonated chelate ligands, has been studied by electrospray ionization mass spectrometry. 1 and 2 crystallize in the triclinic space group and monoclinic space group Cc, respectively, and feature a hitherto not observed triangular metal-ligand skeleton that is characterized by predominantly ferromagnetic exchange coupling between Ni(II) ions. Proof-of-concept infrared reflection–absorption spectroscopy measurements of 1 deposited on a gold substrate indicate that this moisture-stable compound retains its main structural features upon adsorption on the metal surface, which enables subsequent studies of catalytic properties of 1 on a solid support.
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000858632 7001_ $$0P:(DE-HGF)0$$avan Leusen, Jan$$b1
000858632 7001_ $$0P:(DE-HGF)0$$aIzarova, Natalya V.$$b2
000858632 7001_ $$0P:(DE-HGF)0$$aBourone, Svenja D. M.$$b3
000858632 7001_ $$0P:(DE-HGF)0$$aEllern, Arkady$$b4
000858632 7001_ $$0P:(DE-Juel1)130782$$aKögerler, Paul$$b5
000858632 7001_ $$0P:(DE-Juel1)167441$$aMonakhov, Kirill$$b6$$eCorresponding author$$ufzj
000858632 773__ $$0PERI:(DE-600)2000326-2$$a10.1016/j.poly.2018.01.014$$gVol. 144, p. 144 - 151$$p144 - 151$$tPolyhedron$$v144$$x0277-5387$$y2018
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