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@ARTICLE{Schmitz:858632,
      author       = {Schmitz, Sebastian and van Leusen, Jan and Izarova, Natalya
                      V. and Bourone, Svenja D. M. and Ellern, Arkady and
                      Kögerler, Paul and Monakhov, Kirill},
      title        = {{T}riangular {{N}i3} coordination cluster with a
                      ferromagnetically coupled metal-ligand core},
      journal      = {Polyhedron},
      volume       = {144},
      issn         = {0277-5387},
      address      = {Amsterdam [u.a.]},
      publisher    = {Elsevier Science},
      reportid     = {FZJ-2018-07492},
      pages        = {144 - 151},
      year         = {2018},
      abstract     = {The coordination characteristics of a tridentate,
                      π-conjugated Schiff base (HL·SMe) combined with
                      4-(methylthio)benzoic acid (Hbza·SMe) were explored in
                      methanol solution. A two-step aerobic process involving the
                      precursor NiCl2·6H2O afforded the trinuclear coordination
                      compound
                      [NiII3(L·SMe)4(bza·SMe)(MeOH)2]Cl0.5(CH3O)0.5·5.5MeOH·H2O
                      (1), while the precursor Ni(ClO4)2·6H2O resulted in
                      [NiII3(L·SMe)4(bza·SMe)(MeOH)2](ClO4)0.75(CH3O)0.25·1.5MeOH·0.75H2O
                      (2); in both cases the thioether-containing ligands are key
                      to isolation of crystalline products. Their solvent-free
                      cationic motif [Ni3(L·SMe)4(bza·SMe)]+, supported by two
                      different types of monodeprotonated chelate ligands, has
                      been studied by electrospray ionization mass spectrometry. 1
                      and 2 crystallize in the triclinic space group and
                      monoclinic space group Cc, respectively, and feature a
                      hitherto not observed triangular metal-ligand skeleton that
                      is characterized by predominantly ferromagnetic exchange
                      coupling between Ni(II) ions. Proof-of-concept infrared
                      reflection–absorption spectroscopy measurements of 1
                      deposited on a gold substrate indicate that this
                      moisture-stable compound retains its main structural
                      features upon adsorption on the metal surface, which enables
                      subsequent studies of catalytic properties of 1 on a solid
                      support.},
      cin          = {PGI-6 / JARA-FIT},
      ddc          = {540},
      cid          = {I:(DE-Juel1)PGI-6-20110106 / $I:(DE-82)080009_20140620$},
      pnm          = {522 - Controlling Spin-Based Phenomena (POF3-522)},
      pid          = {G:(DE-HGF)POF3-522},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000428829400019},
      doi          = {10.1016/j.poly.2018.01.014},
      url          = {https://juser.fz-juelich.de/record/858632},
}