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| 001 | 858632 | ||
| 005 | 20210130000031.0 | ||
| 024 | 7 | _ | |a 10.1016/j.poly.2018.01.014 |2 doi |
| 024 | 7 | _ | |a 0277-5387 |2 ISSN |
| 024 | 7 | _ | |a 1873-3719 |2 ISSN |
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| 037 | _ | _ | |a FZJ-2018-07492 |
| 082 | _ | _ | |a 540 |
| 100 | 1 | _ | |a Schmitz, Sebastian |0 P:(DE-Juel1)169869 |b 0 |
| 245 | _ | _ | |a Triangular {Ni3} coordination cluster with a ferromagnetically coupled metal-ligand core |
| 260 | _ | _ | |a Amsterdam [u.a.] |c 2018 |b Elsevier Science |
| 336 | 7 | _ | |a article |2 DRIVER |
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| 520 | _ | _ | |a The coordination characteristics of a tridentate, π-conjugated Schiff base (HL·SMe) combined with 4-(methylthio)benzoic acid (Hbza·SMe) were explored in methanol solution. A two-step aerobic process involving the precursor NiCl2·6H2O afforded the trinuclear coordination compound [NiII3(L·SMe)4(bza·SMe)(MeOH)2]Cl0.5(CH3O)0.5·5.5MeOH·H2O (1), while the precursor Ni(ClO4)2·6H2O resulted in [NiII3(L·SMe)4(bza·SMe)(MeOH)2](ClO4)0.75(CH3O)0.25·1.5MeOH·0.75H2O (2); in both cases the thioether-containing ligands are key to isolation of crystalline products. Their solvent-free cationic motif [Ni3(L·SMe)4(bza·SMe)]+, supported by two different types of monodeprotonated chelate ligands, has been studied by electrospray ionization mass spectrometry. 1 and 2 crystallize in the triclinic space group and monoclinic space group Cc, respectively, and feature a hitherto not observed triangular metal-ligand skeleton that is characterized by predominantly ferromagnetic exchange coupling between Ni(II) ions. Proof-of-concept infrared reflection–absorption spectroscopy measurements of 1 deposited on a gold substrate indicate that this moisture-stable compound retains its main structural features upon adsorption on the metal surface, which enables subsequent studies of catalytic properties of 1 on a solid support. |
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| 700 | 1 | _ | |a van Leusen, Jan |0 P:(DE-HGF)0 |b 1 |
| 700 | 1 | _ | |a Izarova, Natalya V. |0 P:(DE-HGF)0 |b 2 |
| 700 | 1 | _ | |a Bourone, Svenja D. M. |0 P:(DE-HGF)0 |b 3 |
| 700 | 1 | _ | |a Ellern, Arkady |0 P:(DE-HGF)0 |b 4 |
| 700 | 1 | _ | |a Kögerler, Paul |0 P:(DE-Juel1)130782 |b 5 |
| 700 | 1 | _ | |a Monakhov, Kirill |0 P:(DE-Juel1)167441 |b 6 |e Corresponding author |u fzj |
| 773 | _ | _ | |a 10.1016/j.poly.2018.01.014 |g Vol. 144, p. 144 - 151 |0 PERI:(DE-600)2000326-2 |p 144 - 151 |t Polyhedron |v 144 |y 2018 |x 0277-5387 |
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