TY - JOUR AU - Yi, Xiaofeng AU - Izarova, Natalya V. AU - Kögerler, Paul TI - The homometallic polyoxotungstate archetype {P 4 W 24 } JO - Chemical communications VL - 54 IS - 18 SN - 1364-548X CY - Cambridge PB - Soc. M1 - FZJ-2018-07493 SP - 2216 - 2219 PY - 2018 AB - Functionalization with terminal organophosphonate and -arsonate groups allows for crystallization and structural characterization of elusive homometallic phosphotungstates of the {PV4WVI24} archetype. 31P NMR measurements reveal moderate stability in aqueous solution for the [(PhPO)2P4W24O92]16− derivative, enabling consecutive reactions as exemplified by the formation of a CoII-{P4W24}-based coordination polymer. LB - PUB:(DE-HGF)16 C6 - pmid:29308478 UR - <Go to ISI:>//WOS:000426701900006 DO - DOI:10.1039/C7CC09175C UR - https://juser.fz-juelich.de/record/858633 ER -