Home > Publications database > The homometallic polyoxotungstate archetype {P 4 W 24 } |
Journal Article | FZJ-2018-07493 |
; ;
2018
Soc.
Cambridge
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Please use a persistent id in citations: doi:10.1039/C7CC09175C
Abstract: Functionalization with terminal organophosphonate and -arsonate groups allows for crystallization and structural characterization of elusive homometallic phosphotungstates of the {PV4WVI24} archetype. 31P NMR measurements reveal moderate stability in aqueous solution for the [(PhPO)2P4W24O92]16− derivative, enabling consecutive reactions as exemplified by the formation of a CoII-{P4W24}-based coordination polymer.
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