Journal Article FZJ-2019-00063

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A Solid Oxide Fuel Cell Operating on Liquid Organic Hydrogen Carrier-Based Hydrogen - A Kinetic Model of the Hydrogen Release Unit and System Performance

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2019
Elsevier New York, NY [u.a.]

International journal of hydrogen energy 44(26), 13794-13806 () [10.1016/j.ijhydene.2019.03.220]

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Abstract: In this paper, a kinetic model for the catalytic dehydrogenation of perhydro dibenzyltoluene (H18-DBT), a well-established Liquid Organic Hydrogen Carrier (LOHC) compound, is presented. Kinetic parameters for hydrogen release at a Pt on alumina catalyst in a temperature range between 260 °C and 310 °C are presented. A Solid Oxide Fuel Cell (SOFC) system model was coupled to the hydrogen release from H18-DBT in order to validate the full sequence of LOHC-bound hydrogen-to-electric power. A system layout is described and investigated according to its transient operating behavior and its efficiency. We demonstrate that the maximum efficiency of LOHC-bound hydrogen-to-electricity is 45% at full load, avoiding any critical conditions for the system components.

Classification:

Contributing Institute(s):
  1. Elektrochemische Verfahrenstechnik (IEK-3)
Research Program(s):
  1. 135 - Fuel Cells (POF3-135) (POF3-135)

Appears in the scientific report 2019
Database coverage:
Medline ; Clarivate Analytics Master Journal List ; Current Contents - Engineering, Computing and Technology ; Ebsco Academic Search ; IF < 5 ; JCR ; NCBI Molecular Biology Database ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Web of Science Core Collection
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 Record created 2019-01-07, last modified 2024-07-08



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