Journal Article FZJ-2019-01507

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Bilayer CrN/CrCoating Modified 316L Stainless Steel Bipolar Plates for High Temperature Polymer Electrolyte Fuel Cells

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2019
Elsevier New York, NY [u.a.]

Journal of power sources 434, 226718 - () [10.1016/j.jpowsour.2019.226718]

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Abstract: In this work, a bilayer CrN/Cr coating was deposited on the surface of a 0.1 mm-thick SS316L specimen with a size of 60 × 60 mm2 by means of a reactive magnetron sputtering method. Using a specially-designed electrochemical cell for simulating the HT-PEFC environment, various electrochemical tests, including potentiodynamic polarization, potentiostatic polarization and EIS, were performed in order to evaluate the anti-corrosion properties and stability of the bilayer CrN/Cr coating in simulated HT-PEFC environments. Additionally, ex-situ characterizations using XRD, SEM + EDX and ICR were carried out to investigate the crystal structure and composition of CrN/Cr coating, surface morphologies and the interfacial contact resistance of samples before and after corrosion tests. The results show that the bilayer CrN/Cr coating could provide a more than 99.9% protective effect on the substrate (SS316L) in the simulated HT-PEFC environment at RT and 130 °C, and reduce the corrosion rates of BPPs more than 600 times in both the simulated cathodic and anodic environments of a HT-PEFC. Furthermore, an ICR value of CrN/Cr SS316L (5.5 mΩ cm2) is around one order of magnitude lower than that of the bare SS316L substrate (47 mΩ cm2) in a typical pressing force for assembling fuel cells (140 N cm−2).

Classification:

Contributing Institute(s):
  1. Elektrochemische Verfahrenstechnik (IEK-3)
Research Program(s):
  1. 135 - Fuel Cells (POF3-135) (POF3-135)

Appears in the scientific report 2019
Database coverage:
Medline ; Clarivate Analytics Master Journal List ; Current Contents - Engineering, Computing and Technology ; Current Contents - Physical, Chemical and Earth Sciences ; Ebsco Academic Search ; IF >= 5 ; JCR ; NCBI Molecular Biology Database ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Web of Science Core Collection
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 Record created 2019-02-18, last modified 2024-07-08



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