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@ARTICLE{Kotov:865028,
author = {Kotov, Vladislav and Koelman, Peter},
title = {{P}lug flow reactor model of the plasma chemical conversion
of {CO}2},
journal = {Plasma sources science and technology},
volume = {28},
number = {9},
issn = {1361-6595},
address = {Bristol},
publisher = {IOP Publ.},
reportid = {FZJ-2019-04593},
pages = {095002},
year = {2019},
abstract = {A 1D plug flow model suitable for describing the
CO<sub>2</sub> conversion into CO in microwave plasma
reactors is proposed. The model is applied together with the
Antwerp data set for the CO<sub>2</sub> reaction kinetics to
calculate parameter scans for a realistic experimental set
up. The energy re-distribution pathways in the model
calculations are analyzed. The analysis shows that despite
the input power is initially deposited mainly into
vibrational states the fast vibrational-translational (VT)
transfer leads to dissociation of CO<sub>2</sub>
predominantly via the thermal quenching mechanism. Solutions
with mitigated VT-losses can be obtained by increasing the
specific input power - power per unit volume. In this regime
the energy efficiency starts to be constrained by reverse
processes.},
cin = {IEK-4},
ddc = {530},
cid = {I:(DE-Juel1)IEK-4-20101013},
pnm = {113 - Methods and Concepts for Material Development
(POF3-113)},
pid = {G:(DE-HGF)POF3-113},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000488012000001},
doi = {10.1088/1361-6595/ab3774},
url = {https://juser.fz-juelich.de/record/865028},
}