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@ARTICLE{Stadler:866412,
      author       = {Stadler, Daniel and Mueller, David N. and Brede, Thomas and
                      Duchoň, Tomáš and Fischer, Thomas and Sarkar, Anirban and
                      Giesen, Margret and Schneider, Claus M. and Volkert, Cynthia
                      A. and Mathur, Sanjay},
      title        = {{M}agnetic {F}ield-{A}ssisted {C}hemical {V}apor
                      {D}eposition of {I}ron {O}xide {T}hin {F}ilms: {I}nfluence
                      of {F}ield–{M}atter {I}nteractions on {P}hase
                      {C}omposition and {M}orphology},
      journal      = {The journal of physical chemistry letters},
      volume       = {10},
      number       = {20},
      issn         = {1948-7185},
      address      = {Washington, DC},
      publisher    = {ACS},
      reportid     = {FZJ-2019-05565},
      pages        = {6253 - 6259},
      year         = {2019},
      abstract     = {Magnetic field-assisted CVD offers a direct pathway to
                      manipulate the evolution of microstructure, phase
                      composition, and magnetic properties of the as-prepared
                      film. We report on the role of applied magnetic fields (0.5
                      T) during a cold-wall CVD deposition of iron oxide from
                      [FeIII(OtBu)3]2 leading to higher crystallinity, larger
                      particulates, and better out-of-plane magnetic anisotropy,
                      if compared with zero-field depositions. Whereas selective
                      formation of homogeneous magnetite films was observed for
                      the field-assisted process, coexistence of hematite and
                      amorphous iron(III) oxide was confirmed under zero-field
                      conditions. Comparison of the coercive field (11 vs 60 mT)
                      indicated lower defect concentration for the field-assisted
                      process with nearly superparamagnetic behavior. X-ray
                      photoemission electron microscopy (X-PEEM) in absorption
                      mode at the O-K and Fe-L3,2 edges confirmed the selective
                      formation of magnetite (field-assisted) and hematite
                      (zero-field) with coexisting amorphous phases, respectively,
                      emphasizing the importance of field–matter interactions in
                      the phase-selective synthesis of magnetic thin films.},
      cin          = {PGI-6},
      ddc          = {530},
      cid          = {I:(DE-Juel1)PGI-6-20110106},
      pnm          = {522 - Controlling Spin-Based Phenomena (POF3-522)},
      pid          = {G:(DE-HGF)POF3-522},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:31500420},
      UT           = {WOS:000492425100040},
      doi          = {10.1021/acs.jpclett.9b02381},
      url          = {https://juser.fz-juelich.de/record/866412},
}