TY  - JOUR
AU  - Kim, Un-Hyuck
AU  - Kuo, Liang-Yin
AU  - Kaghazchi, Payam
AU  - Yoon, Chong S.
AU  - Sun, Yang-Kook
TI  - Quaternary Layered Ni-Rich NCMA Cathode for Lithium-Ion Batteries
JO  - ACS energy letters
VL  - 4
IS  - 2
SN  - 2380-8195
CY  - Washington, DC
PB  - American Chemical Society
M1  - FZJ-2019-06035
SP  - 576 - 582
PY  - 2019
AB  - Li[Ni1–x–yCoxAly]O2 (NCA) and Li[Ni1–x–yCoxMny]O2 (NCM) cathodes have been the archetypes of current high-energy-density cathodes for Li-ion batteries. A hybrid of NCA and NCM cathodes, a quaternary system consisting of Li[Ni0.89Co0.05Mn0.05Al0.01]O2 (NCMA) was benchmarked against NCM and NCA with similar Ni contents. The quaternary NCMA cathode delivered a capacity of 228 mAh g–1 and outperformed the benchmarking cathodes in long-term cycling stability (85% after 1000 cycles). The reduction in the volume change during deintercalation and the enhanced intrinsic mechanical strength confirmed by the single-particle compression test suppressed the microcrack nucleation and propagation. Microcrack suppression was important because microcracks serve as channels for electrolyte infiltration and lead to subsequent surface degradation of internal surfaces. The proposed NCMA cathode provides extra cycling stability, which is essential for electric vehicles, which require a long battery life and improves the thermal stability of the cathode, which contributes to a safer battery.
LB  - PUB:(DE-HGF)16
UR  - <Go to ISI:>//WOS:000458938400030
DO  - DOI:10.1021/acsenergylett.8b02499
UR  - https://juser.fz-juelich.de/record/867277
ER  -