Journal Article

FZJ-2019-06035

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Quaternary Layered Ni-Rich NCMA Cathode for Lithium-Ion Batteries

Kim, U.-H. ; Kuo, L.-Y. ; Kaghazchi, P.FZJ* ; Yoon, C. S. ; Sun, Y.-K. (Corresponding author)

2019
American Chemical Society Washington, DC

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Please use a persistent id in citations: http://hdl.handle.net/2128/23668  doi:10.1021/acsenergylett.8b02499

Abstract: Li[Ni1–x–yCoxAly]O2 (NCA) and Li[Ni1–x–yCoxMny]O2 (NCM) cathodes have been the archetypes of current high-energy-density cathodes for Li-ion batteries. A hybrid of NCA and NCM cathodes, a quaternary system consisting of Li[Ni0.89Co0.05Mn0.05Al0.01]O2 (NCMA) was benchmarked against NCM and NCA with similar Ni contents. The quaternary NCMA cathode delivered a capacity of 228 mAh g–1 and outperformed the benchmarking cathodes in long-term cycling stability (85% after 1000 cycles). The reduction in the volume change during deintercalation and the enhanced intrinsic mechanical strength confirmed by the single-particle compression test suppressed the microcrack nucleation and propagation. Microcrack suppression was important because microcracks serve as channels for electrolyte infiltration and lead to subsequent surface degradation of internal surfaces. The proposed NCMA cathode provides extra cycling stability, which is essential for electric vehicles, which require a long battery life and improves the thermal stability of the cathode, which contributes to a safer battery.

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Contributing Institute(s):

1. Werkstoffsynthese und Herstellungsverfahren (IEK-1)

Research Program(s):

1. 131 - Electrochemical Storage (POF3-131) (POF3-131)

Appears in the scientific report 2019

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Database coverage:
; ; ; Clarivate Analytics Master Journal List ; Current Contents - Engineering, Computing and Technology ; Current Contents - Physical, Chemical and Earth Sciences ; IF >= 10 ; JCR ; SCOPUS ; Science Citation Index Expanded ; Web of Science Core Collection

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