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000867642 1001_ $$0P:(DE-HGF)0$$aContente, Martina Letizia$$b0
000867642 245__ $$aStereoselective Reduction of Prochiral Cyclic 1,3-Diketones Using Different Biocatalysts
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000867642 520__ $$aWe have developed biocatalytic methods for the stereoselective reduction of cyclic prochiral 1,3-diketones for the production of optically active β-hydroxyketones and/or 1,3-diols. The recombinant ketoreductase KRED1-Pglu (formulated as purified catalyst) and whole cells of wild type Escherichia coli DE3 Star were used as biocatalysts, displaying different and sometimes complementary stereoselectivity, thus allowing the preparation of stereochemically pure β-hydroxyketones (12–66% isolated yields, > 99% e.e.) and 1,3-diols (40–60% isolated yields, > 99% e.e.).
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000867642 7001_ $$0P:(DE-HGF)0$$aDall’Oglio, Federica$$b1
000867642 7001_ $$0P:(DE-HGF)0$$aAnnunziata, Francesca$$b2
000867642 7001_ $$0P:(DE-HGF)0$$aMolinari, Francesco$$b3
000867642 7001_ $$0P:(DE-HGF)0$$aRabuffetti, Marco$$b4
000867642 7001_ $$0P:(DE-HGF)0$$aRomano, Diego$$b5
000867642 7001_ $$0P:(DE-HGF)0$$aTamborini, Lucia$$b6
000867642 7001_ $$0P:(DE-Juel1)144643$$aRother, Dörte$$b7$$ufzj
000867642 7001_ $$0P:(DE-HGF)0$$aPinto, Andrea$$b8$$eCorresponding author
000867642 773__ $$0PERI:(DE-600)1501518-x$$a10.1007/s10562-019-03015-y$$p1176-1185$$tCatalysis letters$$v150$$x1572-879X$$y2020
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