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@ARTICLE{Pomaska:872832,
author = {Pomaska, Manuel and Köhler, Malte and Procel Moya, Paul
and Zamchiy, Alexandr and Singh, Aryak and Kim, Do Yun and
Isabella, Olindo and Zeman, Miro and Li, Shenghao and Qiu,
Kaifu and Eberst, Alexander and Smirnov, Vladimir and
Finger, Friedhelm and Rau, Uwe and Ding, Kaining},
title = {{T}ransparent silicon carbide/tunnel {S}i{O}$_{2}$
passivation for c‐{S}i solar cell front side: {E}nabling
{J}$_{sc}$ \> 42 m{A}/cm 2 and i {V}$_{oc}$ of 742 m{V}},
journal = {Progress in photovoltaics},
volume = {28},
number = {4},
issn = {1099-159X},
address = {Chichester},
publisher = {Wiley},
reportid = {FZJ-2020-00302},
pages = {321 - 327},
year = {2020},
abstract = {N‐type microcrystalline silicon carbide (μc‐SiC:H(n))
is a wide bandgap material that is very promising for the
use on the front side of crystalline silicon (c‐Si) solar
cells. It offers a high optical transparency and a suitable
refractive index that reduces parasitic absorption and
reflection losses, respectively. In this work, we
investigate the potential of hot wire chemical vapor
deposition (HWCVD)–grown μc‐SiC:H(n) for c‐Si solar
cells with interdigitated back contacts (IBC). We
demonstrate outstanding passivation quality of
μc‐SiC:H(n) on tunnel oxide (SiO2)–passivated c‐Si
with an implied open‐circuit voltage of 742 mV and a
saturation current density of 3.6 fA/cm2. This excellent
passivation quality is achieved directly after the HWCVD
deposition of μc‐SiC:H(n) at 250°C heater temperature
without any further treatments like recrystallization or
hydrogenation. Additionally, we developed magnesium fluoride
(MgF2)/silicon nitride (SiNx:H)/silicon carbide
antireflection coatings that reduce optical losses on the
front side to only 0.47 mA/cm2 with
MgF2/SiNx:H/μc‐SiC:H(n) and 0.62 mA/cm2 with
MgF2/μc‐SiC:H(n). Finally, calculations with Sentaurus
TCAD simulation using MgF2/μc‐SiC:H(n)/SiO2/c‐Si as
front side layer stack in an IBC solar cell reveal a
short‐circuit current density of 42.2 mA/cm2, an
open‐circuit voltage of 738 mV, a fill factor of $85.2\%$
and a maximum power conversion efficiency of $26.6\%.$},
cin = {IEK-5},
ddc = {690},
cid = {I:(DE-Juel1)IEK-5-20101013},
pnm = {121 - Solar cells of the next generation (POF3-121)},
pid = {G:(DE-HGF)POF3-121},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000507529600001},
doi = {10.1002/pip.3244},
url = {https://juser.fz-juelich.de/record/872832},
}