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001 | 873912 | ||
005 | 20240712113250.0 | ||
024 | 7 | _ | |a 10.1039/C9RA07794D |2 doi |
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100 | 1 | _ | |a Reshetenko, Tatyana |0 0000-0002-4552-062X |b 0 |
245 | _ | _ | |a Nafion film transport properties in a low-Pt PEM fuel cell: impedance spectroscopy study |
260 | _ | _ | |a London |c 2019 |b RSC Publishing |
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520 | _ | _ | |a Unexpected over-linear transport loss in low-Pt PEM fuel cells has been a subject of numerous studies and discussions in literature. Most of the authors agree that these losses are due to oxygen transport in the Nafion film covering Pt/C agglomerates in the cathode catalyst layer (CCL). We develop a model for PEM fuel cell impedance, which takes into account oxygen transport through the film. The model is fitted to experimental impedance spectra of a low-Pt PEM fuel cell. Fitting gives the film thickness in the range of 10 to 13 nm, and the film transport resistivity decreasing from 1.2 s cm−1 to 0.2 s cm−1 as the cell current density increases from 50 to 800 mA cm−2. Fitting returns low value of the through-plane oxygen diffusivity in the CCL, indicating that the low-Pt electrode is partially flooded. |
536 | _ | _ | |a 135 - Fuel Cells (POF3-135) |0 G:(DE-HGF)POF3-135 |c POF3-135 |f POF III |x 0 |
588 | _ | _ | |a Dataset connected to CrossRef |
700 | 1 | _ | |a Kulikovsky, Andrei |0 P:(DE-Juel1)129878 |b 1 |e Corresponding author |
773 | _ | _ | |a 10.1039/C9RA07794D |g Vol. 9, no. 66, p. 38797 - 38806 |0 PERI:(DE-600)2623224-8 |n 66 |p 38797 - 38806 |t RSC Advances |v 9 |y 2019 |x 2046-2069 |
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