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000875246 1001_ $$0P:(DE-Juel1)159457$$aKirchartz, Thomas$$b0$$eCorresponding author
000875246 245__ $$aPhotoluminescence‐Based Characterization of Halide Perovskites for Photovoltaics
000875246 260__ $$aWeinheim$$bWiley-VCH$$c2020
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000875246 520__ $$aPhotoluminescence spectroscopy is a widely applied characterization technique for semiconductor materials in general and halide perovskite solar cell materials in particular. It can give direct information on the recombination kinetics and processes as well as the internal electrochemical potential of free charge carriers in single semiconductor layers, layer stacks with transport layers, and complete solar cells. The correct evaluation and interpretation of photoluminescence requires the consideration of proper excitation conditions, calibration and application of the appropriate approximations to the rather complex theory, which includes radiative recombination, non‐radiative recombination, interface recombination, charge transfer, and photon recycling. In this article, an overview is given of the theory and application to specific halide perovskite compositions, illustrating the variables that should be considered when applying photoluminescence analysis in these materials.
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000875246 7001_ $$0P:(DE-HGF)0$$aMárquez, José A.$$b1
000875246 7001_ $$00000-0002-4023-2178$$aStolterfoht, Martin$$b2
000875246 7001_ $$00000-0002-5750-0693$$aUnold, Thomas$$b3$$eCorresponding author
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