% IMPORTANT: The following is UTF-8 encoded. This means that in the presence % of non-ASCII characters, it will not work with BibTeX 0.99 or older. % Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or % “biber”. @ARTICLE{Basak:875392, author = {Basak, Shibabrata and Migunov, Vadim and Tavabi, Amir Hossein and George, Chandramohan and Lee, Qing and Rosi, Paolo and Arszelewska, Violetta and Ganapathy, Swapna and Vijay, Ashwin and Ooms, Frans G. B. and Schierholz, Roland and Tempel, Hermann and Kungl, Hans and Mayer, Joachim and Dunin-Borkowski, Rafal E. and Eichel, Rüdiger-A. and Wagemaker, Marnix and Kelder, Erik M.}, title = {{O}perando {T}ransmission {E}lectron {M}icroscopy {S}tudy of {A}ll-{S}olid-{S}tate {B}attery {I}nterface: {R}edistribution of {L}ithium among {I}nterconnected {P}articles}, journal = {ACS applied energy materials}, volume = {3}, number = {6}, issn = {2574-0962}, address = {Washington, DC}, publisher = {ACS Publications}, reportid = {FZJ-2020-02001}, pages = {5101–5106}, year = {2020}, note = {Grant: BMBF projects−CatSE (Project 13XP0223A) and LiSi (Project 13XP0224B)}, abstract = {With operando transmission electron microscopy visualizing solid-solid electrode-electrolyte interface of silicon active particles and lithium oxide solid electrolyte as a model system, we show that (de)lithiation (battery cycling) does not require all particles to be in direct contact with electrolytes across length scales of few hundreds of nanometer. A facile lithium redistribution that occurs between interconnected active particles indicates that lithium does not necessarily become isolated in individual particles due to loss of a direct contact. Our results have implications for the design of all-solid-state battery electrodes with improved capacity retention and cyclability.}, cin = {IEK-9 / ER-C-1 / ER-C-2}, ddc = {540}, cid = {I:(DE-Juel1)IEK-9-20110218 / I:(DE-Juel1)ER-C-1-20170209 / I:(DE-Juel1)ER-C-2-20170209}, pnm = {131 - Electrochemical Storage (POF3-131) / 143 - Controlling Configuration-Based Phenomena (POF3-143) / DFG project 167917811 - SFB 917: Resistiv schaltende Chalkogenide für zukünftige Elektronikanwendungen: Struktur, Kinetik und Bauelementskalierung "Nanoswitches" (167917811)}, pid = {G:(DE-HGF)POF3-131 / G:(DE-HGF)POF3-143 / G:(GEPRIS)167917811}, typ = {PUB:(DE-HGF)16}, UT = {WOS:000543715100002}, doi = {10.1021/acsaem.0c00543}, url = {https://juser.fz-juelich.de/record/875392}, }