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@ARTICLE{Reshetenko:878230,
author = {Reshetenko, Tatyana and Serov, Alexey and Odgaard,
Madeleine and Randolf, Günter and Osmieri, Luigi and
Kulikovsky, Andrei},
title = {{E}lectron and proton conductivity of {F}e-{N}-{C} cathodes
for {PEM} fuel cells: {A} model-based electrochemical
impedance spectroscopy measurement},
journal = {Electrochemistry communications},
volume = {118},
issn = {1388-2481},
address = {Amsterdam [u.a.]},
publisher = {Elsevier Science},
reportid = {FZJ-2020-02699},
pages = {106795 -},
year = {2020},
abstract = {Impedance spectra of a PEM fuel cell with three Fe-N-C
cathodes have been measured under the H2/N2 testing regime.
The spectra have been fitted using a recently developed
physics-based impedance model, which takes into account
finite proton (σp) and electron (σe) conductivity of the
oxygen-free cathode catalyst layer. Fitting allowed to
extract numerical data for σp, σe, the double layer
capacitance, and the inductance of cables used for measuring
impedance spectra. The values of σp and σe are close to
what previously found for standard Pt/C electrodes, which is
found for the first time using PGM-free catalysts. The
method enables simultaneous measurement of reference proton
and electron conductivity of PEMFC cathode.},
cin = {IEK-14},
ddc = {540},
cid = {I:(DE-Juel1)IEK-14-20191129},
pnm = {135 - Fuel Cells (POF3-135)},
pid = {G:(DE-HGF)POF3-135},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000567863500001},
doi = {10.1016/j.elecom.2020.106795},
url = {https://juser.fz-juelich.de/record/878230},
}