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@ARTICLE{Duchamp:878260,
author = {Duchamp, M. and Hu, H. and Lam, Y. M. and Dunin-Borkowski,
R. E. and Boothroyd, C. B.},
title = {{STEM} electron beam-induced current measurements of
organic-inorganic perovskite solar cells},
journal = {Ultramicroscopy},
volume = {217},
issn = {0304-3991},
address = {Amsterdam},
publisher = {Elsevier Science},
reportid = {FZJ-2020-02729},
pages = {113047 -},
year = {2020},
abstract = {We describe a new approach for preparing organic-inorganic
perovskite solar cells for electron beam-induced current
(EBIC) measurements in plan-view geometry. This method
substantially reduces sample preparation artefacts, provides
good electrical contact and keeps the preparation steps as
close as possible to those for real devices. Our EBIC images
were acquired simultaneously with annular dark-field
scanning transmission electron microscopy images using a
home-made highly sensitive EBIC amplifier. High-angle
annular dark-field images and energy dispersive X-ray maps
were recorded from the same area immediately afterwards.
This allowed the EBIC contrast to be correlated with regions
containing N and a deficiency of O. The EBIC contrast was
also found to be similar to secondary electron contrast
recorded with a scanning electron microscope. By identifying
the generation and absorption electron processes, we
determine that EBIC cannot be separated from the secondary
electron and absorbed currents. This means that careful
analysis needs to be performed before conclusions can be
made on the origin of the current measured across p-n or
p-i-n junctions.},
cin = {ER-C-1},
ddc = {570},
cid = {I:(DE-Juel1)ER-C-1-20170209},
pnm = {143 - Controlling Configuration-Based Phenomena (POF3-143)},
pid = {G:(DE-HGF)POF3-143},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:32623204},
UT = {WOS:000588011200001},
doi = {10.1016/j.ultramic.2020.113047},
url = {https://juser.fz-juelich.de/record/878260},
}