000878611 001__ 878611
000878611 005__ 20240712113045.0
000878611 0247_ $$2doi$$a10.1002/adfm.202006289
000878611 0247_ $$2ISSN$$a1057-9257
000878611 0247_ $$2ISSN$$a1099-0712
000878611 0247_ $$2ISSN$$a1616-301X
000878611 0247_ $$2ISSN$$a1616-3028
000878611 0247_ $$2Handle$$a2128/26456
000878611 0247_ $$2altmetric$$aaltmetric:88776473
000878611 0247_ $$2WOS$$aWOS:000563908700001
000878611 037__ $$aFZJ-2020-02949
000878611 082__ $$a530
000878611 1001_ $$0P:(DE-Juel1)169878$$aHomann, Gerrit$$b0$$ufzj
000878611 245__ $$aEffective Optimization of High Voltage Solid‐State Lithium Batteries by Using Poly(ethylene oxide)‐Based Polymer Electrolyte with Semi‐Interpenetrating Network
000878611 260__ $$aWeinheim$$bWiley-VCH$$c2020
000878611 3367_ $$2DRIVER$$aarticle
000878611 3367_ $$2DataCite$$aOutput Types/Journal article
000878611 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1607524990_30926
000878611 3367_ $$2BibTeX$$aARTICLE
000878611 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000878611 3367_ $$00$$2EndNote$$aJournal Article
000878611 520__ $$aSolid polymer electrolytes (SPEs) are promising candidates for the realization of lithium metal batteries. However, the popular SPE based on poly(ethylene oxide) (PEO) reveals a “voltage noise”‐failure during charge, for example, with high energy/high voltage electrodes like LiNi0.6Mn0.2Co0.2O2 (NMC622), which can be attributed to short‐circuits via penetrating Li dendrites. This failure disappears when integrating PEO‐based SPE in a semi interpenetrating network, which mainly consists of PEO units, as well. In this work, it is shown that this SPE allows performance improvement via elimination of the crystalline domains without significant sacrifice of mechanical integrity. Hence, a highly amorphous SPE can be obtained by a simple increase of plasticizing Li salts, which overall is beneficial, not only for the ionic conductivity, but also the homogeneity, while remaining mechanically stable and solid in its original shape even after storage at 60 °C for 7 days. These aspects are crucial for the performance of the modified SPE as they can suppress the failure‐causing Li dendrite penetration while the electrochemical aspects, that is, anodic stability, are rather unaffected by the modification and remain stable (4.6 V vs Li│Li+). Overall, this optimized SPE enables stable cycling performance in NMC622│SPE│Li cells, even at 40 °C operation temperature.
000878611 536__ $$0G:(DE-HGF)POF3-131$$a131 - Electrochemical Storage (POF3-131)$$cPOF3-131$$fPOF III$$x0
000878611 588__ $$aDataset connected to CrossRef
000878611 7001_ $$0P:(DE-Juel1)181055$$aStolz, Lukas$$b1$$ufzj
000878611 7001_ $$0P:(DE-Juel1)181017$$aNeuhaus, Kerstin$$b2
000878611 7001_ $$0P:(DE-Juel1)166130$$aWinter, Martin$$b3$$eCorresponding author
000878611 7001_ $$0P:(DE-Juel1)171865$$aKasnatscheew, Johannes$$b4$$eCorresponding author
000878611 773__ $$0PERI:(DE-600)2039420-2$$a10.1002/adfm.202006289$$gp. 2006289 -$$n46$$p2006289 -$$tAdvanced functional materials$$v30$$x1616-3028$$y2020
000878611 8564_ $$uhttps://juser.fz-juelich.de/record/878611/files/pdf.pdf$$yOpenAccess
000878611 8564_ $$uhttps://juser.fz-juelich.de/record/878611/files/pdf.pdf?subformat=pdfa$$xpdfa$$yOpenAccess
000878611 8767_ $$92020-08-24$$d2020-09-04$$eHybrid-OA$$jDEAL$$lDEAL: Wiley
000878611 909CO $$ooai:juser.fz-juelich.de:878611$$pdnbdelivery$$popenCost$$pVDB$$pdriver$$pOpenAPC_DEAL$$popen_access$$popenaire
000878611 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)169878$$aForschungszentrum Jülich$$b0$$kFZJ
000878611 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)181055$$aForschungszentrum Jülich$$b1$$kFZJ
000878611 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)181017$$aForschungszentrum Jülich$$b2$$kFZJ
000878611 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)166130$$aForschungszentrum Jülich$$b3$$kFZJ
000878611 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)171865$$aForschungszentrum Jülich$$b4$$kFZJ
000878611 9131_ $$0G:(DE-HGF)POF3-131$$1G:(DE-HGF)POF3-130$$2G:(DE-HGF)POF3-100$$3G:(DE-HGF)POF3$$4G:(DE-HGF)POF$$aDE-HGF$$bEnergie$$lSpeicher und vernetzte Infrastrukturen$$vElectrochemical Storage$$x0
000878611 9141_ $$y2020
000878611 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS$$d2020-02-26
000878611 915__ $$0StatID:(DE-HGF)0160$$2StatID$$aDBCoverage$$bEssential Science Indicators$$d2020-02-26
000878611 915__ $$0StatID:(DE-HGF)1230$$2StatID$$aDBCoverage$$bCurrent Contents - Electronics and Telecommunications Collection$$d2020-02-26
000878611 915__ $$0StatID:(DE-HGF)0600$$2StatID$$aDBCoverage$$bEbsco Academic Search$$d2020-02-26
000878611 915__ $$0LIC:(DE-HGF)CCBYNCND4$$2HGFVOC$$aCreative Commons Attribution-NonCommercial-NoDerivs CC BY-NC-ND 4.0
000878611 915__ $$0StatID:(DE-HGF)9915$$2StatID$$aIF >= 15$$bADV FUNCT MATER : 2018$$d2020-02-26
000878611 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR$$bADV FUNCT MATER : 2018$$d2020-02-26
000878611 915__ $$0StatID:(DE-HGF)3001$$2StatID$$aDEAL Wiley$$d2020-02-26$$wger
000878611 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection$$d2020-02-26
000878611 915__ $$0StatID:(DE-HGF)0110$$2StatID$$aWoS$$bScience Citation Index$$d2020-02-26
000878611 915__ $$0StatID:(DE-HGF)0111$$2StatID$$aWoS$$bScience Citation Index Expanded$$d2020-02-26
000878611 915__ $$0StatID:(DE-HGF)0510$$2StatID$$aOpenAccess
000878611 915__ $$0StatID:(DE-HGF)0030$$2StatID$$aPeer Review$$bASC$$d2020-02-26
000878611 915__ $$0StatID:(DE-HGF)1150$$2StatID$$aDBCoverage$$bCurrent Contents - Physical, Chemical and Earth Sciences$$d2020-02-26
000878611 915__ $$0StatID:(DE-HGF)0310$$2StatID$$aDBCoverage$$bNCBI Molecular Biology Database$$d2020-02-26
000878611 915__ $$0StatID:(DE-HGF)1160$$2StatID$$aDBCoverage$$bCurrent Contents - Engineering, Computing and Technology$$d2020-02-26
000878611 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline$$d2020-02-26
000878611 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bClarivate Analytics Master Journal List$$d2020-02-26
000878611 9201_ $$0I:(DE-Juel1)IEK-12-20141217$$kIEK-12$$lHelmholtz-Institut Münster Ionenleiter für Energiespeicher$$x0
000878611 9801_ $$aAPC
000878611 9801_ $$aFullTexts
000878611 980__ $$ajournal
000878611 980__ $$aVDB
000878611 980__ $$aUNRESTRICTED
000878611 980__ $$aI:(DE-Juel1)IEK-12-20141217
000878611 980__ $$aAPC
000878611 981__ $$aI:(DE-Juel1)IMD-4-20141217