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@ARTICLE{Pasel:885392,
      author       = {Pasel, Joachim and Häusler, Johannes and Schmitt, Dirk and
                      Valencia, Helen and Meledina, Maria and Mayer, Joachim and
                      Peters, Ralf},
      title        = {{E}thanol {D}ehydrogenation: {A} {R}eaction {P}ath {S}tudy
                      by {M}eans of {T}emporal {A}nalysis of {P}roducts},
      journal      = {Catalysts},
      volume       = {10},
      number       = {10},
      issn         = {2073-4344},
      address      = {Basel},
      publisher    = {MDPI},
      reportid     = {FZJ-2020-03789},
      pages        = {1151 -},
      year         = {2020},
      abstract     = {Conventional fossil fuels such as gasoline or diesel should
                      be substituted in the future by environmentally-friendly
                      alternatives in order to reduce emissions in the transport
                      sector and thus mitigate global warming. In this regard,
                      iso-butanol is very promising as its chemical and physical
                      properties are very similar to those of gasoline. Therefore,
                      ongoing research deals with the development of
                      catalytically-supported synthesis routes to iso-butanol,
                      starting from renewably-generated methanol. This research
                      has already revealed that the dehydrogenation of ethanol
                      plays an important role in the reaction sequence from
                      methanol to iso-butanol. To improve the fundamental
                      understanding of the ethanol dehydrogenation step, the
                      Temporal Analysis of Products (TAP) methodology was applied
                      to illuminate that the catalysts used, Pt/C, Ir/C and Cu/C,
                      are very active in ethanol adsorption. H2 and acetaldehyde
                      are formed on the catalyst surfaces, with the latter quickly
                      decomposing into CO and CH4 under the given reaction
                      conditions. Based on the TAP results, this paper proposes a
                      reaction scheme for ethanol dehydrogenation and acetaldehyde
                      decomposition on the respective catalysts. The samples are
                      characterized by means of N2 sorption and Scanning
                      Transmission Electron Microscopy (STEM).},
      cin          = {IEK-14 / ER-C-2},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IEK-14-20191129 / I:(DE-Juel1)ER-C-2-20170209},
      pnm          = {143 - Controlling Configuration-Based Phenomena (POF3-143)},
      pid          = {G:(DE-HGF)POF3-143},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000584533100001},
      doi          = {10.3390/catal10101151},
      url          = {https://juser.fz-juelich.de/record/885392},
}