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@ARTICLE{Garlatti:885418,
      author       = {Garlatti, Elena and Guidi, Tatiana and Chiesa, Alessandro
                      and Ansbro, Simon and Baker, Michael L. and Ollivier,
                      Jacques and Mutka, Hannu and Timco, Grigore A. and
                      Vitorica-Yrezabal, Inigo and Pavarini, Eva and Santini,
                      Paolo and Amoretti, Giuseppe and Winpenny, Richard E. P. and
                      Carretta, Stefano},
      title        = {{A}nisotropy of {C}o {II} transferred to the {C}r 7 {C}o
                      polymetallic cluster via strong exchange interactions},
      journal      = {Chemical science},
      volume       = {9},
      number       = {14},
      issn         = {2041-6539},
      address      = {Cambridge},
      publisher    = {RSC},
      reportid     = {FZJ-2020-03815},
      pages        = {3555 - 3562},
      year         = {2018},
      abstract     = {The $Cr_7Co$ ring represents a model system to understand
                      how the anisotropy of a $Co^{II}$ ion is transferred to the
                      effective anisotropy of a polymetallic cluster by strong
                      exchange interactions. Combining sizeable anisotropy with
                      exchange interactions is an important point in the
                      understanding and design of new anisotropic molecular
                      nanomagnets addressing fundamental and applicative issues.
                      By combining electron paramagnetic resonance and inelastic
                      neutron scattering measurements with spin Hamiltonian and ab
                      initio calculations, we have investigated in detail the
                      anisotropy of the $Co^{II}$ ion embedded in the
                      antiferromagnetic ring. Our results demonstrate a strong and
                      anisotropic exchange interaction between the Co and the
                      neighbouring Cr ions, which effectively transmits the
                      anisotropy to the whole molecule.},
      ddc          = {540},
      pnm          = {Spin-orbital order-disorder transitions in strongly
                      correlated systems $(jiff46_20161101)$},
      pid          = {$G:(DE-Juel1)jiff46_20161101$},
      typ          = {PUB:(DE-HGF)16},
      doi          = {10.1039/C8SC00163D},
      url          = {https://juser.fz-juelich.de/record/885418},
}