TY - JOUR
AU - Sarwar, Sidra
AU - Sanz, Sergio
AU - van Leusen, Jan
AU - Nichol, Gary S.
AU - Brechin, Euan K.
AU - Kögerler, Paul
TI - Phthalocyanine-polyoxotungstate lanthanide double deckers
JO - Dalton transactions
VL - 49
IS - 46
SN - 1477-9234
CY - London
PB - Soc.
M1 - FZJ-2020-05108
SP - 16638 - 16642
PY - 2020
AB - Acetate ligand metathesis results in the first hybrid [MIII(Pc)(PW11O39)]6− (M = Y, Dy, Tb) double-decker scaffolds, where a phthalocyanate (Pc2−) and one of the conceptually most simple polyoxotungstates, a monolacunary Keggin cluster, are interlinked via a single rare earth ion. Characterisation includes high-resolution mass spectrometry, synchrotron-based single-crystal X-ray diffraction, various spectroscopic and electrochemical methods, and magnetic studies revealing slow relaxation of the magnetisation for the Dy derivate.
LB - PUB:(DE-HGF)16
C6 - 33169769
UR - <Go to ISI:>//WOS:000597124500010
DO - DOI:10.1039/D0DT03716H
UR - https://juser.fz-juelich.de/record/888673
ER -